In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

This Perspective illustrates the defining characteristics of free radical chemistry, beginning
with its rich and storied history. Studies from our laboratory are discussed along with recent …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Electron spins permeate every aspect of science and influence numerous chemical
processes: they underpin transition metal chemistry and biochemistry, mediate …

This Perspective describes general methods for the preparation of polyfunctional zinc
organometallics and their use in Negishi cross-coupling reactions. Recent advances …

Stereochemically defined C-glycosides are prized for their biological activity. Develo** a
catalytic method that comprises non-precious metals to synthesize these C-glycosides …

Cross-couplings of alkyl halides and organometallic species based on single electron
transfer using Ni and Fe catalyst systems have been studied extensively, and separately, for …

The scarcity of precious metals has led to the development of sustainable strategies for
metal‐catalyzed cross‐coupling reactions. The establishment of new catalytic methods …

Conspectus The catalytic cross-coupling reactions of organic halides or related substrates
with organometallic nucleophiles form the cornerstone of many carbon–carbon bond …