Lignin structure and its engineering

J Ralph, C Lapierre, W Boerjan - Current opinion in biotechnology, 2019 - Elsevier
Highlights•New monomers have been discovered, and structural aspects of the lignin
polymer have been refined.•The definition of a lignin monomer has been broadened.• …

Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading

W Schutyser, T Renders, S Van den Bosch… - Chemical society …, 2018 - pubs.rsc.org
In pursuit of more sustainable and competitive biorefineries, the effective valorisation of
lignin is key. An alluring opportunity is the exploitation of lignin as a resource for chemicals …

Lignin-first biomass fractionation: the advent of active stabilisation strategies

T Renders, S Van den Bosch, SF Koelewijn… - Energy & …, 2017 - pubs.rsc.org
During the past decade, a growing scientific community is eagerly seeking for effective lignin
valorisation approaches. Thought-out utilisation of the world's most abundant resource of bio …

[HTML][HTML] Lignin to materials: A focused review on recent novel lignin applications

O Yu, KH Kim - Applied Sciences, 2020 - mdpi.com
In recent decades, advancements in lignin application include the synthesis of polymers,
dyes, adhesives and fertilizers. There has recently been a shift from perceiving lignin as a …

Biomass pretreatment using deep eutectic solvents from lignin derived phenols

KH Kim, T Dutta, J Sun, B Simmons, S Singh - Green chemistry, 2018 - pubs.rsc.org
In future biorefineries, the development of inexpensive and renewable reagents is highly
desirable. In this work, we report a renewable and new class of deep eutectic solvent (DES) …

The cornerstone of realizing lignin value-addition: Exploiting the native structure and properties of lignin by extraction methods

D Huang, R Li, P Xu, T Li, R Deng, S Chen… - Chemical Engineering …, 2020 - Elsevier
The complex interlacing structure among cellulose, hemicellulose and lignin and the unique
properties of lignin itself limit the value-added utilization of the lignin. As the “upstream” …

Phenolic cross-links: building and de-constructing the plant cell wall

E Mnich, N Bjarnholt, A Eudes, J Harholt… - Natural product …, 2020 - pubs.rsc.org
Covering: Up to 2019 Phenolic cross-links and phenolic inter-unit linkages result from the
oxidative coupling of two hydroxycinnamates or two molecules of tyrosine. Free dimers of …

[HTML][HTML] Improve enzymatic hydrolysis of lignocellulosic biomass by modifying lignin structure via sulfite pretreatment and using lignin blockers

C Huang, R Li, W Tang, Y Zheng, X Meng - Fermentation, 2022 - mdpi.com
Even traditional pretreatments can partially remove or degrade lignin and hemicellulose
from lignocellulosic biomass for enhancing its enzymatic digestibility, the remaining lignin in …

Chemical and biological delignification of biomass: a review

D Schieppati, NA Patience, F Galli, P Dal… - Industrial & …, 2023 - ACS Publications
Lignin is a highly abundant biopolymer with a complex polyphenolic structure, making it a
potential source of aromatic precursors, polymers, and energy. However, its thermal stability …

Lignin engineering in forest trees

A Chanoca, L De Vries, W Boerjan - Frontiers in Plant Science, 2019 - frontiersin.org
Wood is a renewable resource that is mainly composed of lignin and cell wall
polysaccharides. The polysaccharide fraction is valuable as it can be converted into pulp …