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Metallaheteroboranes with group 16 elements: Aspects of synthesis, framework and reactivity
Metallaheteroborane clusters containing group-16 elements as cluster constituents were
initially of interest solely for the synthesis of high-nuclearity clusters. However, owing to …
initially of interest solely for the synthesis of high-nuclearity clusters. However, owing to …
Construction of a Boron Chain on a Single Metal by Dehydrocoupling of Borane Ligands
C Luz, K Oppel, L Endres, RD Dewhurst… - Journal of the …, 2024 - ACS Publications
Borane coordination, B–H borane bond activation, and borane catenation via metal-
mediated dehydrocoupling to form electron-precise B–B bonds are reported. The reaction of …
mediated dehydrocoupling to form electron-precise B–B bonds are reported. The reaction of …
Hexagonal Bipyramidal [Ta2B6]−/0 Clusters: B6 Rings as Structural Motifs
It has been a long‐sought goal in cluster science to discover stable atomic clusters as
building blocks for cluster‐assembled nanomaterials, as exemplified by the fullerenes and …
building blocks for cluster‐assembled nanomaterials, as exemplified by the fullerenes and …
Supraicosahedral polyhedra in metallaboranes: synthesis and structural characterization of 12-, 15-, and 16-vertex rhodaboranes
Syntheses and structural characterization of supraicosahedral rhodaborane clusters are
reported. Reaction of [(Cp* RhCl2) 2],(Cp*= η5-C5Me5) with [LiBH4· thf] followed by …
reported. Reaction of [(Cp* RhCl2) 2],(Cp*= η5-C5Me5) with [LiBH4· thf] followed by …
First‐Row Transition‐Metal–Diborane and–Borylene Complexes
A combined experimental and quantum chemical study of Group 7 borane, trimetallic triply
bridged borylene and boride complexes has been undertaken. Treatment of [{Cp* CoCl} …
bridged borylene and boride complexes has been undertaken. Treatment of [{Cp* CoCl} …
Chemistry of diruthenium analogue of pentaborane (9) with heterocumulenes: toward novel trimetallic cubane-type clusters
Reactions of the CS2 and CO2 heterocumulene ligands with nido-ruthenaborane cluster [1,
2-(Cp* Ru) 2 (μ-H) 2B3H7], 1, were explored (Cp*= pentamethylcyclopentadienyl) …
2-(Cp* Ru) 2 (μ-H) 2B3H7], 1, were explored (Cp*= pentamethylcyclopentadienyl) …
Synthesis and Structural Characterization of New Divanada‐and Diniobaboranes Containing Chalcogen Atoms
The reaction of [CpnMCl4− x](M= V: n= 2, x= 2; M= Nb: n= 1, x= 0; Cp= η5‐C5H5) with
LiBH4⋅ THF followed by thermolysis in the presence of dichalcogenide ligands E2R2 (E= S …
LiBH4⋅ THF followed by thermolysis in the presence of dichalcogenide ligands E2R2 (E= S …
Chemistry of Diruthenium and Dirhodium Analogues of Pentaborane (9): Synthesis and Characterization of Metal N, S‐Heterocyclic Carbene and B‐Agostic …
Building upon our earlier results on the synthesis of electron‐precise transition‐metal–boron
complexes, we continue to investigate the reactivity of pentaborane (9) and tetraborane (10) …
complexes, we continue to investigate the reactivity of pentaborane (9) and tetraborane (10) …
Trithia-diborinane and Bis(bridging-boryl) Complexes of Ruthenium Derived from a [BH3(SCHS)]− Ion
The field of diborinane is sparsely explored area, and not many compounds are structurally
characterized. The room-temperature reaction of [{Cp* RuCl (μ-Cl)} 2](Cp*= η5-C5Me5) with …
characterized. The room-temperature reaction of [{Cp* RuCl (μ-Cl)} 2](Cp*= η5-C5Me5) with …
Fine Tuning of Metallaborane Geometries: Chemistry of Metallaboranes of Early Transition Metals Derived from Metal Halides and Monoborane Reagents
Abstract Reaction of [CpnMCl4− x](M= V: n= x= 2; M= Nb: n= 1, x= 0) or [Cp* TaCl4](Cp= η5‐
C5H5, Cp*= η5‐C5Me5), with [LiBH4⋅ thf] at− 70° C followed by thermolysis at 85° C in the …
C5H5, Cp*= η5‐C5Me5), with [LiBH4⋅ thf] at− 70° C followed by thermolysis at 85° C in the …