Magnetic Slow Relaxation in a Metal–Organic Framework Made of Chains of Ferromagnetically Coupled Single‐Molecule Magnets

G Huang, G Fernandez‐Garcia… - … A European Journal, 2018 - Wiley Online Library
We report the study of a Dy‐based metal–organic framework (MOF) with unprecedented
magnetic properties. The compound is made of nine‐coordinated DyIII magnetic building …

Magnetic properties and magnetocaloric effect of Ln= Dy, Tb carborane-based metal–organic frameworks

Z Li, A Arauzo, JG Planas, E Bartolomé - Dalton Transactions, 2024 - pubs.rsc.org
We present the synthesis and magneto-thermal properties of carborane-based lanthanide
metal–organic frameworks (MOFs) with the formula {[(Ln) 3 (mCB-L) 4 (NO3)(DMF) n]· Solv} …

Lanthanide furoate complexes as promising systems with double effects–From suppression of mycobacteria to potential bioimaging

MA Uvarova, ME Nikiforova, MA Shmelev… - Inorganica Chimica …, 2024 - Elsevier
Several ternary complexes of rare earth ions (Gd 3+, Eu 3+, Sm 3+) with 3-furoic (H3fur)/5-
nitro-2-furoic (Hnfur) acids and 1, 10-phenanthroline (phen) have been synthesized …

The paradigm of magnetic molecule in quantum matter: Slow molecular spin relaxation

V Sirenko, F Bartolomé Usieto… - Low Temperature …, 2024 - pubs.aip.org
The quantum nature of single-ion magnets, single-molecule magnets, and single-chain
magnets has been manifested among other phenomena by magnetic hysteresis due to slow …

Magnetic relaxation of lanthanide-based molecular magnets

E Bartolomé, A Arauzo, J Luzón, J Bartolomé… - Handbook of Magnetic …, 2017 - Elsevier
Molecular magnets containing lanthanide ions have been receiving an increasing level of
attention during the last years. The applicability of molecular magnets on foreseeable …

How to link theory and experiment for single-chain magnets beyond the Ising model: magnetic properties modeled from ab initio calculations of molecular fragments

M Böhme, W Plass - Chemical Science, 2019 - pubs.rsc.org
Magnetic properties of coordination polymers like single-chain magnets (SCMs) are based
on magnetic domains, which are formed due to magnetic exchange between neighboring …

Two chain-based TbIII/DyIII complexes derived from m-nitrobenzoic acid with totally different structures and magnetic properties

TF Zheng, XM Tian, SL Yao, C Cao, JB Cai… - Journal of Molecular …, 2018 - Elsevier
Two Ln III complexes derived from one aromatic monocarboxylate ligand, namely [Tb 2
(mnba) 6 (H 2 O) 4] n (1) and [Dy 2 (mnba) 4 (μ 3-OH) 2 (H 2 O)] n (2)(Hmnba= m …

Slow magnetic relaxation in ladder-type and single-strand 2p–3d–4f heterotrispin chains

M Yang, J **e, Z Sun, L Li, JP Sutter - Inorganic Chemistry, 2017 - ACS Publications
Ladder-type and chain 2p–3d–4f complexes based on a bridging nitronyl nitroxide radical,
namely,[LnCu (hfac) 5 (NIT-Ph-p-OCH2trz)]· 0.5 C6H14 [Ln= Y (1a), Dy (1b)] and [LnCu …

Heteronuclear {Tb x Eu 1− x} furoate 1D polymers presenting luminescent properties and SMM behavior

E Bartolomé, J Bartolomé, A Arauzo, J Luzón… - Journal of Materials …, 2018 - pubs.rsc.org
We report the synthesis, crystal structure and photo-magnetic properties of novel Tb/Eu
polymeric complexes of general formula {TbxEu1− x (α-fur) 3 (H2O) 3} n, supported by 2 …

Light-induced magnetic switching in a coumarin-based Tb single molecule magnet

E Bartolomé, A Arauzo, J Luzón… - Journal of Materials …, 2025 - pubs.rsc.org
We present the intriguing magneto-optical properties of the lanthanide complex [Tb (coum) 3
(batho)]·[0.7 EtOH], named Tb–batho, based on coum= 3-acetyl-4-hydroxylato-coumarin and …