Combustion synthesis in nanostructured reactive systems

AS Mukasyan, AS Rogachev, STR Aruna - Advanced Powder Technology, 2015 - Elsevier
New classes of reactive systems that are characterized by nano-scale heterogeneity and
possess extremely high reactivity, as compared to that for similar reactive systems with micro …

Mechanical activation of heterogeneous exothermic reactions in powder mixtures

AS Rogachev - Russian Chemical Reviews, 2019 - iopscience.iop.org
The review concerns the results of recent experimental, theoretical and applied studies on
mechanical activation of reactive powder compositions and self-propagating high …

Experimental investigation of milling regimes in planetary ball mill and their influence on structure and reactivity of gasless powder exothermic mixtures

AS Rogachev, DO Moskovskikh, AA Nepapushev… - Powder Technology, 2015 - Elsevier
The dynamics of ball motion during high energy planetary ball milling was investigated in-
situ using high speed video recording. The trajectories and velocities of the balls were …

Direct combustion synthesis of silicon carbide nanopowder from the elements

AS Mukasyan, YC Lin, AS Rogachev… - Journal of the …, 2013 - Wiley Online Library
Direct synthesis of silicon carbide (SiC) nanopowders (size 50–200 nm, BET~ 20 m2/g) in Si–
C system is conducted in an inert atmosphere (argon) using a self‐propagating high …

Solid-flame: Experimental validation

CE Shuck, KV Manukyan, S Rouvimov… - Combustion and …, 2016 - Elsevier
The tantalum–carbon reactive system possesses a high energy of reaction with an adiabatic
combustion temperature of 2743 K, which is significantly below the melting points of the …

Mechanochemical synthesis of methylammonium lead iodide perovskite

KV Manukyan, AV Yeghishyan… - Journal of Materials …, 2016 - Springer
A mechanically induced solid-state reaction method for the synthesis of organic–inorganic
hybrid perovskites, such as methylammonium lead iodide (CH 3 NH 3 PbI 3) is reported. The …

Shock loading of granular Ni/Al composites. Part 2: Shock-induced chemistry

MJ Cherukara, TC Germann, EM Kober… - The Journal of …, 2016 - ACS Publications
We use molecular dynamics simulations to characterize the chemical processes resulting
from the shock compaction of a loosely packed granular reactive composite of Ni and Al. For …

Irradiation-enhanced reactivity of multilayer Al/Ni nanomaterials

KV Manukyan, W Tan, RJ deBoer… - … applied materials & …, 2015 - ACS Publications
We have investigated the effect of accelerated ion beam irradiation on the structure and
reactivity of multilayer sputter deposited Al/Ni nanomaterials. Carbon and aluminum ion …

Ceramics from self-sustained reactions: Recent advances

AS Mukasyan, DO Moskovskikh… - Journal of the European …, 2020 - Elsevier
Specific applications of self-sustained reactions to fabricate advanced ceramics, along with
details such as synthesis conditions, mechanism of microstructure formation, and material …

Kinetics and mechanism of ignition in reactive Al/Ni nanostructured materials

K Manukyan, J Pauls, C Shuck… - The Journal of …, 2018 - ACS Publications
A high-speed electrothermography approach is applied to investigate the mechanism and
kinetics for nanostructured Al/Ni foils. Application of the Kolmogorov–Johnson–Mehl–Avrami …