Recent progress in homogeneous light-driven hydrogen evolution using first-row transition metal catalysts

A Mazzeo, S Santalla, C Gaviglio, F Doctorovich… - Inorganica Chimica …, 2021 - Elsevier
The rich chemistry, low cost and availability offered by first-row transition metals have
inspired many researchers to focus on the design, preparation and testing of a wide plethora …

Photocatalytic hydrogen production with a molecular cobalt complex in alkaline aqueous solutions

P Wang, N Le, JD McCool, B Donnadieu… - Journal of the …, 2024 - ACS Publications
The thermodynamic favorability of an alkaline solution for the oxidation of water suggests the
need for develo** hydrogen evolution reaction (HER) catalysts that can function in basic …

Recent progress in homogeneous molecular photoredox catalysis towards hydrogen evolution reaction and future perspective

L Mawrie, F Rahman, MA Ali, S Gazi - Applied Catalysis A: General, 2023 - Elsevier
The bad impact of fossil fuel and the need of green energy resources have directed many
researchers to develop various light-driven, CO 2 non emissive hydrogen producing …

Ligand-centered hydrogen evolution with Ni (II) and Pd (II) DMTH

CA Phipps, DT Hofsommer, MJ Toda… - Inorganic …, 2022 - ACS Publications
In this study, we report a pair of electrocatalysts for the hydrogen evolution reaction (HER)
based on the noninnocent ligand diacetyl-2-(4-methyl-3-thiosemicarbazone)-3-(2 …

Development of strong visible‐light‐absorbing cyclometalated iridium (iii) complexes for robust and efficient light‐driven hydrogen production

SC Yiu, PY Ho, YY Kwok, X He, Y Wang… - … A European Journal, 2022 - Wiley Online Library
Weak light absorption of common Ir (III) complexes (eg, using phenylpyridine as the ligand)
has hindered their applications in photocatalytic hydrogen generation from water as an …

Ligand-based electronic effects on the electrocatalytic hydrogen production by thiosemicarbazone nickel complexes

M Papadakis, A Barrozo, T Straistari, N Queyriaux… - Dalton …, 2020 - pubs.rsc.org
This work reports on the synthesis and characterization of a series of mononuclear
thiosemicarbazone nickel complexes that display significant catalytic activity for hydrogen …

Carbon dots for photocatalytic H 2 production in aqueous media with molecular Co catalysts

K Ladomenou, G Landrou, G Charalambidis… - Sustainable Energy & …, 2021 - pubs.rsc.org
Carbon dots and nitrogen doped carbon dots were effectively synthesized and
characterized. Their use as light harvesters was examined in the presence of three different …

Photosensitizers for H2 Evolution Based on Charged or Neutral Zn and Sn Porphyrins

E Giannoudis, E Benazzi, J Karlsson… - Inorganic …, 2020 - ACS Publications
We report a comparison between a series of zinc and tin porphyrins as photosensitizers for
photochemical hydrogen evolution using cobaloxime complexes as molecular catalysts …

Spectral, thermal and DFT studies of novel nickel (II) complexes of 2-benzoylpyridine-N4-methyl-3-thiosemicarbazone: crystal structure of a square planar azido-nickel …

K Jayakumar, EB Seena, MRP Kurup, S Kaya… - Journal of Molecular …, 2022 - Elsevier
Novel six Ni (II) complexes of an NNS donor 2-benzoylpyridine-N 4-methyl-3-
thiosemicarbazone (HL) are synthesized and characterized. Various physicochemical …

Heteroleptic thiolate diamine nickel complexes: Noble-free-metal catalysts in electrocatalytic and light-driven hydrogen evolution reaction

F Kamatsos, M Drosou, CA Mitsopoulou - International Journal of Hydrogen …, 2021 - Elsevier
Three mononuclear heteroleptic nickel complexes bearing the non-innocent o-
aminobenzenethiolate (2-amnt) ligand and different diamine ligands, namely,[Ni (2-amnt)(o …