In this review, the pivotal achievements and recent advances in catalytic asymmetric aza‐
DAR reported up to 2020 are retrospectively considered and their potency for …

In contrast to the widely explored methods for the asymmetric synthesis of molecules
bearing a single stereocenter or adjacent stereocenters, the concurrent construction of 1, 3 …

The development of efficient and straightforward methods for obtaining all optically active
isomers of structurally rigid spirocycles from readily available starting materials is of great …

Since its discovery more than a century ago, the Friedel–Crafts reaction has manifested itself
as a powerful method for the introduction of carbon substituents to arenes. Despite its …

Catalytic enantioselective synthesis methodologies have been actively explored and
developed owing to the significance of chiral molecules and their utilities. In particular …

Unnatural chiral α-tertiary amino acids containing two different carbon-based substituents at
the α-carbon centre are widespread in biologically active molecules. This sterically rigid …

Chiral α-aryl glycines play a key role in the preparation of some bioactive products, however,
their catalytic asymmetric synthesis is far from being satisfactory. Herein, we report an …

Transition‐metal catalyzed enantioconvergent cross‐coupling of tertiary alkyl halides with
ammonia offers a rapid avenue to chiral unnatural α, α‐disubstituted amino acids. However …

Enantioenriched α‐tertiary‐α‐aminoacid and α‐chiral‐β‐aminoacid derivatives play an
important role in biological science and pharmaceutical chemistry. Thus, the development of …

A direct alkoxycarbonylation/cyclization reaction is accomplished under visible light-induced
photoredox catalysis. With this approach, a variety of ester-substituted indolo [2, 1-a] …