Femtochemistry: atomic‐scale dynamics of the chemical bond using ultrafast lasers (Nobel Lecture)

AH Zewail - Angewandte Chemie International Edition, 2000 - Wiley Online Library
Over many millennia, humankind has thought to explore phenomena on an ever shorter time
scale. In this race against time, femtosecond resolution (1 fs= 10− 15 s) is the ultimate …

Quantum scattering calculations on chemical reactions

SC Althorpe, DC Clary - Annual review of physical chemistry, 2003 - annualreviews.org
▪ Abstract This review discusses recent quantum scattering calculations on bimolecular
chemical reactions in the gas phase. This theory provides detailed and accurate predictions …

Femtochemistry: Atomic-scale dynamics of the chemical bond

AH Zewail - The Journal of Physical Chemistry A, 2000 - ACS Publications
This anthology, which is adapted from the Nobel Lecture, gives an overview of the field of
Femtochemistry from a personal perspective, encompassing our research at Caltech and …

Imaging nucleophilic substitution dynamics

J Mikosch, S Trippel, C Eichhorn, R Otto, U Lourderaj… - Science, 2008 - science.org
Anion-molecule nucleophilic substitution (SN2) reactions are known for their rich reaction
dynamics, caused by a complex potential energy surface with a submerged barrier and by …

Recent advances in quantum dynamics of bimolecular reactions

DH Zhang, H Guo - Annual review of physical chemistry, 2016 - annualreviews.org
In this review, we survey the latest advances in theoretical understanding of bimolecular
reaction dynamics in the past decade. The remarkable recent progress in this field has been …

[LIVRE][B] Theories of molecular reaction dynamics: the microscopic foundation of chemical kinetics

NE Henriksen, FY Hansen - 2018 - books.google.com
This book deals with a central topic at the interface of chemistry and physics--the
understanding of how the transformation of matter takes place at the atomic level. Building …

Transform-limited pulses are not optimal for resonant multiphoton transitions

N Dudovich, B Dayan, SMG Faeder, Y Silberberg - Physical Review Letters, 2001 - APS
Maximizing nonlinear light-matter interactions is a primary motive for compressing laser
pulses to achieve ultrashort transform limited pulses. Here we show how, by appropriately …

Predictive a priori pressure-dependent kinetics

AW Jasper, KM Pelzer, JA Miller, E Kamarchik… - Science, 2014 - science.org
The ability to predict the pressure dependence of chemical reaction rates would be a great
boon to kinetic modeling of processes such as combustion and atmospheric chemistry. This …

Chemical reaction dynamics with molecular beams

P Casavecchia - Reports on Progress in Physics, 2000 - iopscience.iop.org
This review describes advances which have occurred during the past decade in chemical
reaction dynamics using crossed molecular beams. After a brief historical introduction …

Quantum interference in H + HD → H2 + D between direct abstraction and roaming insertion pathways

Y **e, H Zhao, Y Wang, Y Huang, T Wang, X Xu… - Science, 2020 - science.org
Understanding quantum interferences is essential to the study of chemical reaction
dynamics. Here, we provide an interesting case of quantum interference between two …