Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …

Recent advances in organic chemistry and materials chemistry have enabled the porosity of
new materials to be accurately controlled on the nanometer scale. In this context, metal …

The pores in metal–organic frameworks (MOFs) can be functionalized by placing chemical
entities along the backbone and within the backbone. This chemistry is enabled by the …

Hydrogenated nitrogen heterocyclic compounds play a critical role in the pharmaceutical,
polymer, and agrochemical industries. Recent studies on partial hydrogenation of nitrogen …

Supported metal nanoparticles are the most widely investigated heterogeneous catalysts in
catalysis community. The size of metal nanostructures is an important parameter in …

When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …

Atomically dispersing metal atoms on supports provides an ideal strategy for maximizing
metal utilization for catalysis, which is particularly important for fabricating cost‐effective …