Dataset design for building models of chemical reactivity

P Raghavan, BC Haas, ME Ruos, J Schleinitz… - ACS Central …, 2023 - ACS Publications
Models can codify our understanding of chemical reactivity and serve a useful purpose in
the development of new synthetic processes via, for example, evaluating hypothetical …

Computational methods for asymmetric catalysis

S Pinus, J Genzling, M Burai-Patrascu, N Moitessier - Nature Catalysis, 2024 - nature.com
Impressive progress in computational asymmetric catalysis has been made in the past
twenty years owing to advancements in algorithm and method development for predicting …

A data-driven workflow for assigning and predicting generality in asymmetric catalysis

IO Betinol, J Lai, S Thakur, JP Reid - Journal of the American …, 2023 - ACS Publications
The development of chiral catalysts that can provide high enantioselectivities across a wide
assortment of substrates or reaction range is a priority for many catalyst design efforts. While …

AI for organic and polymer synthesis

X Hong, Q Yang, K Liao, J Pei, M Chen, F Mo… - Science China …, 2024 - Springer
Recent years have witnessed the transformative impact from the integration of artificial
intelligence with organic and polymer synthesis. This synergy offers innovative and …

Towards a comprehensive data infrastructure for redox-active organic molecules targeting non-aqueous redox flow batteries

R Duke, V Bhat, P Sornberger, SA Odom, C Risko - Digital Discovery, 2023 - pubs.rsc.org
The shift of energy production towards renewable, yet at times inconsistent, resources like
solar and wind have increased the need for better energy storage solutions. An emerging …

Classification of hemilabile ligands using machine learning

I Kevlishvili, C Duan, HJ Kulik - The Journal of Physical Chemistry …, 2023 - ACS Publications
Hemilabile ligands have the capacity to partially disengage from a metal center, providing a
strategy to balance stability and reactivity in catalysis, but they are not straightforward to …

A genetic optimization strategy with generality in asymmetric organocatalysis as a primary target

S Gallarati, P van Gerwen, R Laplaza, L Brey… - Chemical …, 2024 - pubs.rsc.org
A catalyst possessing a broad substrate scope, in terms of both turnover and
enantioselectivity, is sometimes called “general”. Despite their great utility in asymmetric …

COMPAS-2: a dataset of cata-condensed hetero-polycyclic aromatic systems

E Mayo Yanes, S Chakraborty, R Gershoni-Poranne - Scientific Data, 2024 - nature.com
Polycyclic aromatic systems are highly important to numerous applications, in particular to
organic electronics and optoelectronics. High-throughput screening and generative models …

Leveraging chemistry foundation models to facilitate structure focused retrieval augmented generation in multi-agent workflows for catalyst and materials design

NH Park, TJ Callahan, JL Hedrick, T Erdmann… - arxiv preprint arxiv …, 2024 - arxiv.org
Molecular property prediction and generative design via deep learning models has been the
subject of intense research given its potential to accelerate development of new, high …

Combining molecular quantum mechanical modeling and machine learning for accelerated reaction screening and discovery

N Casetti, JE Alfonso‐Ramos… - … –A European Journal, 2023 - Wiley Online Library
Molecular quantum mechanical modeling, accelerated by machine learning, has opened the
door to high‐throughput screening campaigns of complex properties, such as the activation …