Water splitting for large-scale hydrogen production is a method for storing sustainable but
intermittent energy sources. Oxygen evolution reaction (OER) through the water oxidation …

The recent focus on develo** high-valent non-oxo-metal complexes for late transition
metals has proven to be an effective strategy to study the rich chemistry of these high-valent …

This study confirms the hypothesis that [MnCl3 (OPPh3) 2](1) and acetonitrile-solvated
MnCl3 (ie,[MnCl3 (MeCN) x]) can be used as synthons to prepare Mn (III) chloride …

Nickel catalysis has experienced a renaissance over the recent two decades, driven by its
ability to access diverse oxidation states (0 to+ 4) and unique reactivity. This feature article …

High-valent metal species are often invoked as intermediates during enzymatic and
synthetic catalytic cycles. Anionic donors are often required to stabilize such high-valent …

Mononuclear nickel (II) and nickel (III) complexes of a bisamidate-bisalkoxide ligand,(NMe4)
2 [NiII (HMPAB)](1) and (NMe4)[NiIII (HMPAB)](2), respectively, have been synthesized and …

The participation of both ligand and the metal center in the redox events has been
recognized as one of the ways to attain the formal high valent complexes for the late 3d …

A facile, cost-effective, and sustainable synthesis of substituted triazines from primary
alcohols by newly synthesized nickel pincer-type complexes (1–3) has been described …

The pincer type new benzamide derivative ligands; N, N'-(2, 2′-azenidiil-bis (2, 1-
phenylene)) bis (2-methylbenzamide)(H 3 L 1), N, N'-(2, 2′-azenidiil-bis (2, 1-phenylene)) …

Nickel-based catalysts are employed in organometallic transformations such as C–C/C–
heteroatom cross-coupling reactions. The work presented here describes the reactivity of …