From molecules to interactions to crystal engineering: mechanical properties of organic solids

S Saha, MK Mishra, CM Reddy… - Accounts of chemical …, 2018 - ACS Publications
Conspectus Mechanical properties of organic molecular crystals have been noted and
studied over the years but the complexity of the subject and its relationship with diverse …

Elastically flexible molecular crystals

AJ Thompson, AIC Orué, AJ Nair, JR Price… - Chemical Society …, 2021 - pubs.rsc.org
The discovery of molecular single crystals that display interesting elastic behaviour has
generated excitement regarding their potential applications as it has upended the common …

Atomic resolution of structural changes in elastic crystals of copper(II) acetylacetonate

A Worthy, A Grosjean, MC Pfrunder, Y Xu, C Yan… - Nature …, 2018 - nature.com
Single crystals are typically brittle, inelastic materials. Such mechanical responses limit their
use in practical applications, particularly in flexible electronics and optical devices. Here we …

Mechanically flexible organic crystals achieved by introducing weak interactions in structure: supramolecular shape synthons

GR Krishna, R Devarapalli, G Lal… - Journal of the American …, 2016 - ACS Publications
Controlling mechanical properties of ordered organic materials remains a formidable
challenge, despite their great potential for high performance mechanical actuators …

Crystal adaptronics: mechanically reconfigurable elastic and superelastic molecular crystals

E Ahmed, DP Karothu, P Naumov - Angewandte Chemie …, 2018 - Wiley Online Library
Mechanically reconfigurable molecular crystals—ordered materials that can adapt to
variable operating and environmental conditions by deformation, whereby they attain motility …

Multi‐stimuli‐induced mechanical bending and reversible fluorescence switching in a single organic crystal

X Zheng, X Liu, L Liu, X Li, S Jiang, C Niu… - Angewandte …, 2022 - Wiley Online Library
Fluorescent single crystals that respond to multiple external stimuli are of great interest in
molecular machines, sensors, and displays. The integration of photo‐or acid‐induced …

Stimuli-responsive flexible organic crystals

W Wu, K Chen, T Wang, N Wang, X Huang… - Journal of Materials …, 2023 - pubs.rsc.org
Organic crystals, possessing both flexibility and stimuli-responsive properties, are attractive
candidates as smart materials, namely sensors, actuators, optoelectronic devices …

Thermally twistable, photobendable, elastically deformable, and self‐healable soft crystals

P Gupta, DP Karothu, E Ahmed, P Naumov… - Angewandte …, 2018 - Wiley Online Library
The first example of a smart crystalline material, the 2: 1 cocrystal of probenecid and 4, 4′‐
azopyridine, which responds reversibly to multiple external stimuli (heat, UV light, and …

Crystal engineering of hand-twisted helical crystals

S Saha, GR Desiraju - Journal of the American Chemical Society, 2017 - ACS Publications
A strategy is outlined for the design of hand-twisted helical crystals. The starting point in the
exercise is the one-dimensional (1D) plastic crystal, 1, 4-dibromobenzene, which is then …

A Flexible Organic Single Crystal with Plastic‐Twisting and Elastic‐Bending Capabilities and Polarization‐Rotation Function

H Liu, Z Lu, B Tang, C Qu, Z Zhang… - Angewandte …, 2020 - Wiley Online Library
Flexible organic single crystals capable of plastic or elastic deformations have a variety of
potential applications. Although the integration of plasticity and elasticity in a crystal is …