The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds

DC Crans, JJ Smee, E Gaidamauskas… - Chemical reviews, 2004 - ACS Publications
Vanadium is a trace element, which may be beneficial and possibly essential in humans1
but certainly essential for some living organisms. 2r11 Metal ions and thus vanadium ions …

Hydrolysis, Ligand Exchange, and Redox Properties of Vanadium Compounds: Implications of Solution Transformation on Biological, Therapeutic, and Environmental …

R Dinda, E Garribba, D Sanna, DC Crans… - Chemical …, 2025 - ACS Publications
Vanadium is a transition metal with important industrial, technological, biological, and
biomedical applications widespread in the environment and in living beings. The different …

In vitro study of the insulin-mimetic behaviour of vanadium (IV, V) coordination compounds

D Rehder, J Costa Pessoa, CF Geraldes… - JBIC Journal of …, 2002 - Springer
A representative set of vanadium (IV and V) compounds in varying coordination
environments has been tested in the concentration range 1 to 10–6 mM, using transformed …

Metal speciation in health and medicine represented by iron and vanadium

DC Crans, KA Woll, K Prusinskas, MD Johnson… - Inorganic …, 2013 - ACS Publications
The influence of metals in biology has become more and more apparent within the past
century. Metal ions perform essential roles as critical scaffolds for structure and as catalysts …

Oxovanadium (IV) and oxovanadium (V) complexes relevant to biological systems

EJ Baran - Journal of Inorganic Biochemistry, 2000 - Elsevier
Different aspects of the coordination chemistry of oxovanadium (IV) and oxovanadium (V),
relevant to the bioinorganic chemistry of vanadium, are presented. Some of the investigated …

Vanadium (IV)− citrate complex interconversions in aqueous solutions. A pH-dependent synthetic, structural, spectroscopic, and magnetic study

M Tsaramyrsi, M Kaliva, A Salifoglou… - Inorganic …, 2001 - ACS Publications
Citrate is abundantly encountered in biological fluids as a natural metal ion chelator.
Vanadium participates in biological processes as a catalyst in the active sites of …

[HTML][HTML] Interaction of iron (III) with taste enhancers: Potential of Fe (III) salts with inosine monophosphate or guanosine monophosphate for food fortification

J Bijlsma, P Buglyó, E Farkas, KP Velikov, JP Vincken… - LWT, 2023 - Elsevier
Iron interactions in iron-fortified savory concentrates lead to undesirable discoloration, even
when poorly-water soluble iron salts such as ferric pyrophosphate (Fe 4 PP 3) are used. This …

Correlations of synthetic, spectroscopic, structural, and speciation studies in the biologically relevant cobalt (II)− citrate system: the tale of the first aqueous dinuclear …

N Kotsakis, CP Raptopoulou, V Tangoulis… - Inorganic …, 2003 - ACS Publications
Synthetic efforts targeting soluble species of Co (II) with the low molecular mass
physiological ligand citric acid led to the isolation of the first dinuclear complex [Co2 …

Interaction of VO2+ ion with human serum transferrin and albumin

D Sanna, E Garribba, G Micera - Journal of inorganic biochemistry, 2009 - Elsevier
The complexation of VO2+ ion with the high molecular mass components of the blood
serum, human serum transferrin (hTf) and albumin (HSA), has been re-examined using EPR …

New developments in the comprehension of the biotransformation and transport of insulin-enhancing vanadium compounds in the blood serum

D Sanna, G Micera, E Garribba - Inorganic chemistry, 2010 - ACS Publications
The possible biotransformations in the blood serum of four representative insulin-enhancing
vanadium compounds,[VO (6-mepic) 2], cis-[VO (pic) 2 (H2O)],[VO (acac) 2], and [VO (dhp) …