Influence of the Norbornene Anchor Group in Ru-Mediated Ring-Opening Metathesis Polymerization: Synthesis of Bottlebrush Polymers

SJ Scannelli, M Alaboalirat, D Troya… - Macromolecules, 2023 - ACS Publications
Ring-opening metathesis polymerization (ROMP) mediated by Grubbs' third-generation
catalyst [G3,(H2IMes)(Cl) 2 (pyr) 2RuCHPh] is widely used to make bottlebrush polymers by …

Tricyclononenes and tricyclononadienes as efficient monomers for controlled ROMP: understanding structure–propagation rate relationships and enabling facile post …

LJ Kilgallon, TP McFadden, MS Sigman… - Chemical Science, 2024 - pubs.rsc.org
Grubbs 3rd-generation (G3) pre-catalyst-initiated ring-opening metathesis polymerization
(ROMP) remains an indispensable tool in the polymer chemist's toolbox. Tricyclononenes …

Ring-opening metathesis polymerization of norbornene–benzoladderene (macro) monomers

SJ Scannelli, M Alaboalirat, D Troya, JB Matson - Polymer Chemistry, 2023 - pubs.rsc.org
Norbornene-based monomers are common starting points in ring-opening metathesis
polymerization (ROMP) due to their high ring strain, and recent reports highlight how the …

Marriage of Organic and Grubbs Catalysts for Tandem Synthesis of Bottlebrush Polyesters

Y Huang, C Zhao, B Zhang, H Li, J Zhao - ACS Macro Letters, 2023 - ACS Publications
Bottlebrush polymers (BBPs) have gained wide attention for their special characters, such as
rigid main/side chains, stemming from the exceedingly high graft density. This study aims to …

Effect of macromonomer chemical structure on the rate of grafting-through ring-opening metathesis polymerization

KC McCleary-Petersen, Y Feng, D Guironnet - Polymer Chemistry, 2025 - pubs.rsc.org
Ring-opening metathesis polymerization (ROMP) of norbornenyl macromonomers (MM) has
become a preferred method to synthesize bottlebrush (BB) polymers with perfect grafting …

Synthesis of branched bottlebrushes by the combination of ATRP, Pd (II)-initiated isocyanide polymerization, and ROMP

B Chu, H Zou - New Journal of Chemistry, 2024 - pubs.rsc.org
Branched bottlebrushes are a unique class of nanostructured polymers, and their versatile
synthesis is of crucial significance. In this work, a bifunctional initiator was synthesized …

Tricyclononenes and Tricyclononadienes as Efficient Monomers for ROMP: Understanding Structure–Propagation Rate Relationships and Enabling Facile Post …

L Kilgallon, T McFadden, M Sigman, J Johnson - 2024 - chemrxiv.org
Grubbs 3rd-generation (G3) pre-catalyst-initiated ring-opening metathesis polymerization
(ROMP) remains an indispensable tool in the polymer chemist's toolbox. Tricyclononenes …

Aqueous self-assembly of cylindrical and tapered bottlebrush block copolymers

C Vu, NA Amara, M Alaboalirat, E Nativ-Roth, R Zalk… - 2024 - chemrxiv.org
Self-assembly of amphiphilic bottlebrush block copolymers (BCPs), which have backbones
with two types of densely grafted side chains, is less well understood compared to their …