Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications

MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

Mild metal-catalyzed C–H activation: examples and concepts

T Gensch, MN Hopkinson, F Glorius… - Chemical Society …, 2016 - pubs.rsc.org
Organic reactions that involve the direct functionalization of non-activated C–H bonds
represent an attractive class of transformations which maximize atom-and step-economy …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Metal‐Catalyzed Annulations through Activation and Cleavage of C− H Bonds

M Gulías, JL Mascareñas - Angewandte Chemie International …, 2016 - Wiley Online Library
The exponential increase in the number of catalytic transformations that involve a metal‐
promoted activation of hitherto considered inert C− H bonds is promoting a fundamental …

Recent advances in chelation-assisted site-and stereoselective alkenyl C–H functionalization

J Zhang, X Lu, C Shen, L Xu, L Ding… - Chemical Society …, 2021 - pubs.rsc.org
Olefinic C–H functionalization represents an atom-and step economic approach to valuable
olefin derivatives from simpler ones, but controlling the selectivity remains a challenge …

Recent advances in transition metal-catalyzed olefinic C–H functionalization

B Liu, L Yang, P Li, F Wang, X Li - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Transition metal-catalyzed directed C–H activation has emerged as an increasingly powerful
tool for the synthesis of important organic building blocks, organic materials and natural …

Versatile synthetic platform for 1, 2, 3-triazole chemistry

DP Vala, RM Vala, HM Patel - Acs Omega, 2022 - ACS Publications
1, 2, 3-Triazole scaffolds are not obtained in nature, but they are still intensely investigated
by synthetic chemists in various fields due to their excellent properties and green synthetic …

Asymmetric dearomatization of phenols

W Sun, G Li, L Hong, R Wang - Organic & Biomolecular Chemistry, 2016 - pubs.rsc.org
This review summarizes the recent advances in the field of asymmetric dearomatization of
phenols and their applications in the total synthesis of some complex natural products. The …

All-carbon quaternary centers in natural products and medicinal chemistry: recent advances

T Ling, F Rivas - Tetrahedron, 2016 - Elsevier
A remaining challenge in the synthetic chemistry field is formation of all-carbon quaternary
centers, a feature found in many natural products, particularly in spirocycle systems. 1 …

Rhodium-catalyzed C–H activation of phenacyl ammonium salts assisted by an oxidizing C–N bond: a combination of experimental and theoretical studies

S Yu, S Liu, Y Lan, B Wan, X Li - Journal of the American …, 2015 - ACS Publications
Rh (III)-catalyzed C–H activation assisted by an oxidizing directing group has evolved to a
mild and redox-economic strategy for the construction of heterocycles. Despite the success …