Homogeneous and heterogeneous catalysts for hydrogenation of CO 2 to methanol under mild conditions
In the context of a carbon neutral economy, catalytic CO2 hydrogenation to methanol is one
crucial technology for CO2 mitigation providing solutions for manufacturing future fuels …
crucial technology for CO2 mitigation providing solutions for manufacturing future fuels …
Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …
energy is a long-standing challenge in both fundamental science and industry. In recent …
Bio-Inspired Mn(I) Complexes for the Hydrogenation of CO2 to Formate and Formamide
Develo** new, efficient catalysts that contain Earth-abundant metals and simple, robust
ligands for CO2 hydrogenation is important to create cost-effective processes of CO2 …
ligands for CO2 hydrogenation is important to create cost-effective processes of CO2 …
Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
ES Gulyaeva, ES Osipova, R Buhaibeh… - Coordination Chemistry …, 2022 - Elsevier
Rapidly emerging application of organometallic manganese complexes incorporating less
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …
H2 Oxidation over Supported Au Nanoparticle Catalysts: Evidence for Heterolytic H2 Activation at the Metal–Support Interface
T Whittaker, KBS Kumar, C Peterson… - Journal of the …, 2018 - ACS Publications
Water adsorbed at the metal–support interface (MSI) plays an important role in multiple
reactions. Due to its importance in CO preferential oxidation (PrOx), we examined H2 …
reactions. Due to its importance in CO preferential oxidation (PrOx), we examined H2 …
Balancing the Seesaw in Mn-Catalyzed N-Heteroarene Hydrogenation: Mechanism-Inspired Catalyst Design for Simultaneous Taming of Activation and Transfer of …
Recently, Mn-catalyzed hydrogenation reactions have gained significant interest due to their
importance in various challenging transformations. Among several classes of organic …
importance in various challenging transformations. Among several classes of organic …
The rise of manganese-catalyzed reduction reactions
P Schlichter, C Werlé - Synthesis, 2022 - thieme-connect.com
Recent developments in manganese-catalyzed reducing transformations—hydrosilylation,
hydroboration, hydrogenation, and transfer hydrogenation—are reviewed herein. Over the …
hydroboration, hydrogenation, and transfer hydrogenation—are reviewed herein. Over the …
Comparative CO2 Hydrogenation Catalysis with MACHO-type Manganese Complexes
A pair of manganese complexes containing MACHO-type pincer ligands bearing a
secondary amine,[HN {CH2CH2 (P i Pr2)} 2] MnH (CO) 2, which can participate in pathways …
secondary amine,[HN {CH2CH2 (P i Pr2)} 2] MnH (CO) 2, which can participate in pathways …
Hydricity of 3d transition metal complexes from density functional theory: a benchmarking study
AS Goodfellow, M Bühl - Molecules, 2021 - mdpi.com
A range of modern density functional theory (DFT) functionals have been benchmarked
against experimentally determined metal hydride bond strengths for three first-row TM …
against experimentally determined metal hydride bond strengths for three first-row TM …
Controlling Hydrogen Evolution during Photoreduction of CO2 to Formic Acid Using [Rh(R-bpy)(Cp*)Cl]+ Catalysts: A Structure–Activity Study
The photochemical reduction of CO2 to formic acid catalyzed by a series of [Rh (4, 4′-R-
bpy)(Cp*) Cl]+ and [Rh (5, 5′-COOH-bpy)(Cp*) Cl]+ complexes (Cp …
bpy)(Cp*) Cl]+ and [Rh (5, 5′-COOH-bpy)(Cp*) Cl]+ complexes (Cp …