A review of defect structure and chemistry in ceria and its solid solutions

R Schmitt, A Nenning, O Kraynis, R Korobko… - Chemical Society …, 2020‏ - pubs.rsc.org
Ceria and its solid solutions play a vital role in several industrial processes and devices.
These include solar energy-to-fuel conversion, solid oxide fuel and electrolyzer cells …

Rare earth doped ceria: The complex connection between structure and properties

M Coduri, S Checchia, M Longhi, D Ceresoli… - Frontiers in …, 2018‏ - frontiersin.org
The need for high efficiency energy production, conversion, storage and transport is serving
as a robust guide for the development of new materials. Materials with physical-chemical …

Oxygen-defective electrostrictors for soft electromechanics

VB Tinti, JK Han, V Frederiksen, H Chen… - Science …, 2024‏ - science.org
Electromechanical metal oxides, such as piezoceramics, are often incompatible with soft
polymers due to their crystallinity requirements, leading to high processing temperatures …

Chemical lattice strain in nonstoichiometric oxides: an overview

DS Tsvetkov, VV Sereda, DA Malyshkin… - Journal of Materials …, 2022‏ - pubs.rsc.org
Strong coupling between the chemical composition and crystal lattice dimensions resulting
in the contraction or expansion of a material upon change of its chemical composition is …

Cu, Sm co-do** effect on the CO oxidation activity of CeO2. A combined experimental and density functional study

AA AlKhoori, K Polychronopoulou, A Belabbes… - Applied Surface …, 2020‏ - Elsevier
The co-do** effect of a rare earth (RE) metal and a transition metal (TM) on ceria oxidation
catalysis through the evaluation of samarium-copper co-doped catalysts with Ce-Sm-xCu-O …

Electronic structure and room temperature ferromagnetism in Gd‐doped cerium oxide nanoparticles for hydrogen generation via photocatalytic water splitting

S Soni, N Chouhan, RK Meena, S Kumar… - Global …, 2019‏ - Wiley Online Library
Enhanced visible light photocatalytic activity of Gd‐doped CeO2 nanoparticles (NPs) is
experimentally demonstrated, whereas there are very few reports on this mechanism with …

Green synthetic fuels: Renewable routes for the conversion of non-fossil feedstocks into gaseous fuels and their end uses

E Rozzi, FD Minuto, A Lanzini, P Leone - Energies, 2020‏ - mdpi.com
Innovative renewable routes are potentially able to sustain the transition to a decarbonized
energy economy. Green synthetic fuels, including hydrogen and natural gas, are considered …

Correlation of oxygen defects, oxide-ion conductivity and dielectric relaxation to electronic structure and room temperature ferromagnetic properties of Yb3+ doped …

HR Khakhal, S Kumar, D Patidar, S Kumar… - Materials Science and …, 2023‏ - Elsevier
Ce 1-x Yb x O 2 nanoparticles synthesized using co-precipitation route were studied for
properties like structural, optical, impedance and X-ray Photoelectron Spectroscopy …

[HTML][HTML] Electromechanical coupling in alkaline-earth doped-ceria ceramics

VB Tinti, A Kabir, DZ de Florio, V Esposito - Acta Materialia, 2024‏ - Elsevier
Oxygen-deficient cerium oxide ceramics exhibit an anomalously high electromechanical
response called giant electrostriction. This feature has been linked to the polarization and …

Rare-earth-doped ceria systems and their performance as solid electrolytes: A puzzling tangle of structural issues at the average and local scale

C Artini - Inorganic Chemistry, 2018‏ - ACS Publications
Rare-earth (RE)-doped ceria systems, in particular when RE≡ Nd, Sm, or Gd, are well-
known to be characterized by high values of ionic conductivity in the intermediate …