The use of ynamides in organic synthesis has gained significant attention due to their ability
to provide access to complex molecular structures through transformations such as 1, 2 …

Ynamide, a unique species with inherited polarization of nitrogen lone pair electron to triple
bond, has been largely used for the developement of novel synthetic methods and the …

The synthesis of stereodefined tetrasubstituted alkenes bearing four different functional
groups is challenging. Herein, we disclose a 100% atom-economic and highly regio-and …

We synthesized tetrasubstituted olefins regioselectively and stereoselectively from ynamides
and internal alkynes with sulfonyl iodides under blue LEDs in few minutes. The key features …

The Sc (III)-catalyzed [2, 3]-sigmatropic rearrangement of sulfonium ylides derived from
azoalkenes has been established. Owing to the absence of a carbenoid intermediate, this …

The palladium‐catalyzed silylcyanation of ynamides is described. This reaction is fully
regioselective, delivering tetrasubstituted 2‐aminoacrylonitriles derivatives exclusively …

A cationic palladium-catalyzed arylalkenylation of ynamides is presented. The putative
keteniminium arylpalladium intermediate likely dictates the regioselective carbopalladation …

The radical chemistry of ynamides has recently drawn the attention of synthetic organic
chemists to the construction of various N-heterocyclic compounds. Nevertheless, the …

Disclosed herein is a rhodium (III)-catalyzed intramolecular cyclization of ynamides with
propargyl esters. A variety of highly functionalized 2, 5-dihydropyrroles were obtained in …

A metal-free TMSOTf-catalyzed [4+ 2] annulation of ynamides with β-(2-aminophenyl)-α, β-
ynones enables the regiospecific and facile assembly of 2-aminoquinoline frameworks. The …