Asymmetric catalysis has been recognized as the most enabling strategy for accessing
chiral molecules in enantioenriched forms. Catalytic asymmetric dearomatization is an …

Covering: 2000 up to 2019. Catalytic asymmetric dearomatization (CADA) reactions have
witnessed considerable development in recent years. As the most extensively studied sub …

The first catalytic asymmetric construction of 3, 3′‐bisindole skeletons bearing both axial
and central chirality has been established by organocatalytic asymmetric addition reactions …

Covering: 2013–2018 Natural products bearing quaternary carbon stereocenters have
attracted tremendous interest from the synthetic community due to their diverse biological …

Catalytic asymmetric dearomatization (CADA) reactions offer an efficient strategy for directly
converting aromatic compounds into chiral cyclic molecules. Cascade dearomative …

While interest in the synthetic chemistry of radical cations continues to grow, controlling
enantioselectivity in the reactions of these intermediates remains a challenge. Based on …

Copper-catalyzed decarboxylative reactions of propargylic cyclic carbonates/carbamates
enable the efficient construction of widely available skeletons such as allenes, ethynyl …

Prenylation is a ubiquitous process common to almost all living organisms, and a key
transformation in organic synthesis. Dearomative prenylation reactions of tryptophan …

A novel chiral spirocyclic amide (SPA)-derived triazolium organocatalyst has been designed
and demonstrated to effect asymmetric homo-and heterodialkylations of various …

Construction of contiguous all‐carbon quaternary stereogenic centers is a long‐standing
challenge in synthetic organic chemistry. In this report, a phosphine‐catalyzed …