Recent progress in on-surface synthesis of nanoporous graphene materials

T Qin, T Wang, J Zhu - Communications Chemistry, 2024 - nature.com
Nanoporous graphene (NPG) materials are generated by removing internal degree-3
vertices from graphene and introducing nanopores with specific topological structures …

Hexatopic vertex-directed approach to vinylene-linked covalent organic frameworks with heteroporous topologies

Z Zhang, S Bi, F Meng, X Li, M Li, K Mou… - Journal of the …, 2023 - ACS Publications
AD 3 h-symmetric hexatopic monomer was first prepared by attaching the three-fold ditopic
moiety 2, 6-dimethylpyridine to the meta-positions of a phenyl ring. It was further condensed …

Orbital-symmetry effects on magnetic exchange in open-shell nanographenes

Q Du, X Su, Y Liu, Y Jiang, C Li, KK Yan, R Ortiz… - Nature …, 2023 - nature.com
Open-shell nanographenes appear as promising candidates for future applications in
spintronics and quantum technologies. A critical aspect to realize this potential is to design …

Synthesis of highly luminescent chiral nanographene

JK Li, XY Chen, WL Zhao, YL Guo… - Angewandte Chemie …, 2023 - Wiley Online Library
Chiral nanographenes with both high fluorescence quantum yields (ΦF) and large
dissymmetry factors (glum) are essential to the development of circularly polarized …

Circumpentacene with Open‐Shell Singlet Diradical Character

Q Jiang, H Wei, X Hou, C Chi - Angewandte Chemie, 2023 - Wiley Online Library
Circumacenes (CAs) are a distinctive type of benzenoid polycyclic aromatic hydrocarbons
where an acene unit is completely enclosed by a layer of outer fused benzene rings. Despite …

Heteroatom‐Edged [4] Triangulene: Facile Synthesis and Two‐Dimensional On‐Surface Self‐Assemblies

C Chen, J Lu, Y Lv, Y Yan, Q Sun… - Angewandte Chemie …, 2022 - Wiley Online Library
Triangulenes have attracted enormous interest in organic chemistry and materials science,
but suffer from their high instability towards oxygen. Embedding heteroatoms into …

Boron-containing Triangulenes and Their Analogues: Synthesis, Properties, and Applications

Z Chang, C Chen, XY Wang - Chemistry Letters, 2023 - academic.oup.com
Triangulenes are attracting tremendous interest due to their unique structures and appealing
properties. However, the low stability of triangulenes under ambient conditions has …

On-surface synthesis of enetriynes

N Cao, B Yang, A Riss, J Rosen, J Björk… - Nature …, 2023 - nature.com
Belonging to the enyne family, enetriynes comprise a distinct electron-rich all-carbon
bonding scheme. However, the lack of convenient synthesis protocols limits the associated …

Predicting the HOMO-LUMO gap of benzenoid polycyclic hydrocarbons via interpretable machine learning

F Zheng, Z Zhu, J Lu, Y Yan, H Jiang, Q Sun - Chemical Physics Letters, 2023 - Elsevier
While the experimental investigations and quantum chemistry methods have made
significant progress on the exploration of electronic properties of benzenoid polycyclic …

On-surface synthesis of nitrogen-doped nanographene with an [18] annulene pore on Ag (111)

K Sun, D Li, T Kaihara, S Minakata, Y Takeda… - Communications …, 2023 - nature.com
On-surface synthesis is of importance to fabricate low dimensional carbon-based
nanomaterials with atomic precision. Here, we synthesize nitrogen-doped nanographene …