Recent advances in the design of afterglow materials: mechanisms, structural regulation strategies and applications

X Yang, GIN Waterhouse, S Lu, J Yu - Chemical Society Reviews, 2023 - pubs.rsc.org
Afterglow materials are attracting widespread attention owing to their distinctive and long-
lived optical emission properties which create exciting opportunities in various fields. Recent …

Recent Developments on Understanding Charge Transfer in Molecular Electron Donor‐Acceptor Systems

X Chen, X Zhang, X **ao, Z Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
Charge transfer (CT) in molecular electron donor‐acceptor systems is pivotal for artificial
photosynthesis, photocatalysis, photovoltaics and fundamental photochemistry. We …

Constructing high-efficiency orange-red thermally activated delayed fluorescence emitters by three-dimension molecular engineering

L Hua, Y Liu, B Liu, Z Zhao, L Zhang, S Yan… - Nature …, 2022 - nature.com
Preparing high-efficiency solution-processable orange-red thermally activated delayed
fluorescence (TADF) emitters remains challenging. Herein, we design a series of emitters …

Singlet‐Triplet Energy Inversion in Carbon Nitride Photocatalysts

A Actis, M Melchionna, G Filippini… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Time‐resolved EPR (TR‐EPR) demonstrates the formation of well‐defined spin
triplet excitons in carbon nitride. This permits to experimentally probe the extent of the triplet …

Understanding of complex spin up-conversion processes in charge-transfer-type organic molecules

HS Kim, SH Lee, S Yoo, C Adachi - Nature communications, 2024 - nature.com
Despite significant progress made over the past decade in thermally activated delayed
fluorescence (TADF) molecules as a material paradigm for enhancing the performance of …

Enhancing operational stability of OLEDs based on subatomic modified thermally activated delayed fluorescence compounds

S Jung, WL Cheung, S Li, M Wang, W Li… - Nature …, 2023 - nature.com
The realization of operationally stable blue organic light-emitting diodes is a challenging
issue across the field. While device optimization has been a focus to effectively prolong …

Dielectric control of reverse intersystem crossing in thermally activated delayed fluorescence emitters

AJ Gillett, A Pershin, R Pandya, S Feldmann… - Nature materials, 2022 - nature.com
Thermally activated delayed fluorescence enables organic semiconductors with charge
transfer-type excitons to convert dark triplet states into bright singlets via reverse intersystem …

Computational tools for the simulation and analysis of spin-polarized EPR spectra

CE Tait, MD Krzyaniak, S Stoll - Journal of Magnetic Resonance, 2023 - Elsevier
The EPR spectra of paramagnetic species induced by photoexcitation typically exhibit
enhanced absorptive and emissive features resulting from sublevel populations that differ …

Detection of the Dark States in Thermally Activated Delayed Fluorescence (TADF) Process of Electron Donor‐Acceptor Dyads: Insights from Optical Transient …

X Zhang, X Zhao, K Ye, J Zhao - Chemistry–A European …, 2023 - Wiley Online Library
The photophysical processes involved in the electron donor‐acceptor thermally activated
delayed fluorescence (TADF) emitters are complicated and controversial. The recent …

Long-Lived Charge-Separated State in Naphthalimide–Phenothiazine Compact Electron Donor–Acceptor Dyads: Effect of Molecular Conformation Restriction and …

X **ao, Y Yan, AA Sukhanov, S Doria… - The Journal of …, 2023 - ACS Publications
To study the charge separation (CS) and long-lived CS state, we prepared a series of dyads
based on naphthalimide (NI, electron acceptor) and phenothiazine (PTZ, electron donor) …