[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time
A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …
perspective of how information can be stored. The current bit, occupying few hundreds of …
Symmetry strategies for high performance lanthanide-based single-molecule magnets
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …
Strong axiality in a dysprosium (III) bis (borolide) complex leads to magnetic blocking at 65 K
Substituted dysprosocenium complexes of the type [Dy (Cp R) 2]+ exhibit slow magnetic
relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …
relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …
A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …
them at the forefront of the race toward high-temperature single-molecule magnets and …
High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets
KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
Single-molecule magnets beyond a single lanthanide ion: the art of coupling
YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …
On approaching the limit of molecular magnetic anisotropy: a near‐perfect pentagonal bipyramidal dysprosium (III) single‐molecule magnet
We report a monometallic dysprosium complex,[Dy (OtBu) 2 (py) 5][BPh4](5), that shows the
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …
A stable pentagonal bipyramidal Dy (III) single-ion magnet with a record magnetization reversal barrier over 1000 K
Single-molecule magnets (SMMs) with a large spin reversal barrier have been recognized to
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …
exhibit slow magnetic relaxation that can lead to a magnetic hysteresis loop. Synthesis of …
Symmetry-supported magnetic blocking at 20 K in pentagonal bipyramidal Dy (III) single-ion magnets
Single-molecule magnets (SMMs) that can be trapped in one of the bistable magnetic states
separated by an energy barrier are among the most promising candidates for high-density …
separated by an energy barrier are among the most promising candidates for high-density …
Molecular magnetism
NF Chilton - Annual Review of Materials Research, 2022 - annualreviews.org
Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …
than synthesis and has strong links with other disciplines across the physical sciences …