The present review offers an overview of nonclassical (eg, with no pre-or in situ activation of
a carboxylic acid partner) approaches for the construction of amide bonds. The review aims …

The carbon− carbon triple bond of alkynes is one of the basic functional groups, its reactions
belonging to the foundations of organic chemistry. In the past decades, acetylene chemistry …

The completely revised third edition of this four-volume classic is fully updated and now
includes such topics as as CH-activation and multicomponent reactions. It describes the …

A metallaphotoredox‐catalyzed strategy for the selective and divergent aminocarbonylation
of alkynes with amines and 1 atm of CO is reported. This synergistic protocol not only …

Various olefins can be smoothly transformed in the presence of a Pd‐based catalyst system
and (hetero) aromatic amines or nitroarenes to synthetically interesting amides in good …

Ruthenium-and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides
with alkenes were developed. These methods provide an efficient route for the synthesis of …

A class of novel diphosphine ligands bearing pyridine substituents was designed and
synthesized for the first time. The resulting palladium complexes of L1 allow for chemo-and …

The catalyzed addition of carbon monoxide to unsaturated compounds has drawn
considerable attention over the past decade where more structurally complex molecules are …

The palladium-catalyzed regioselective alkoxycarbonylation of allenes with aliphatic
alcohols allows to produce synthetically useful α, β-and β, γ-unsaturated esters in good …

Entering the iron age: The first general method for iron‐catalyzed monocarbonylation of
alkynes has been developed. A range of structurally diverse cinnamides and acrylamides …