Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

Renaissance of strong metal–support interactions

M Xu, M Peng, H Tang, W Zhou, B Qiao… - Journal of the American …, 2024 - ACS Publications
Strong metal–support interactions (SMSIs) have emerged as a significant and cutting-edge
area of research in heterogeneous catalysis. They play crucial roles in modifying the …

Spin-mediated promotion of Co catalysts for ammonia synthesis

K Zhang, A Cao, LH Wandall, J Vernieres, J Kibsgaard… - Science, 2024 - science.org
Over the past two decades, there has been growing interest in develo** catalysts to
enable Haber-Bosch ammonia synthesis under milder conditions than currently pertain …

Dynamic interplay between metal nanoparticles and oxide support under redox conditions

H Frey, A Beck, X Huang, JA van Bokhoven… - Science, 2022 - science.org
The dynamic interactions between noble metal particles and reducible metal-oxide supports
can depend on redox reactions with ambient gases. Transmission electron microscopy …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Operando Electron Microscopy of Catalysts: The Missing Cornerstone in Heterogeneous Catalysis Research?

SW Chee, T Lunkenbein, R Schlögl… - Chemical …, 2023 - ACS Publications
Heterogeneous catalysis in thermal gas-phase and electrochemical liquid-phase chemical
conversion plays an important role in our modern energy landscape. However, many of the …

Efficient overall water splitting of a suspended photocatalyst boosted by metal-support interaction

Y Qi, B Zhang, G Zhang, Z Zheng, T **e, S Chen, G Ma… - Joule, 2024 - cell.com
Strong metal-support interaction (SMSI) has been widely discussed for activity promotion of
heterogeneous catalysis, but the effect of SMSI on photocatalysis remains unclear. Here, we …

Self‐accommodation induced electronic metal–support interaction on ruthenium site for alkaline hydrogen evolution reaction

C Li, SH Kim, HY Lim, Q Sun, Y Jiang… - Advanced …, 2023 - Wiley Online Library
Tuning the metal‐support interaction of supported metal catalysts has been found to be the
most effective approach to modulating electronic structure and improving catalytic …

The critical impacts of ligands on heterogeneous nanocatalysis: A review

L Lu, S Zou, B Fang - Acs Catalysis, 2021 - ACS Publications
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …

Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites

Z Li, S Ji, Y Liu, X Cao, S Tian, Y Chen, Z Niu… - Chemical …, 2019 - ACS Publications
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …