Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Recent years have seen a marked increase in the occurrence of sulfoximines in the
chemical sciences, often presented as valuable motifs for medicinal chemistry. This has …

Conspectus The chemistry of hypervalent iodine (III) compounds has gained great interest
over the past 30 years. Hypervalent iodine (III) compounds show valuable ionic reactivity …

A new system for NH transfer is developed for the preparation of sulfoximines, which are
emerging as valuable motifs for drug discovery. The protocol employs readily available …

Advances in hypervalent iodine chemistry have put the field on the precipice of a second
golden age; the first being pioneered in the 1990s. During that period, C–C bond forming …

This review summarizes the structural and synthetic aspects of heterocyclic molecules
incorporating an atom of a hypervalent main-group element. The term “hypervalent” has …

Sulfoximines are emerging as valuable new isosteres for use in medicinal chemistry, with
the potential to modulate physicochemical properties. Recent developments in synthetic …

X-ray crystallography data revealed the dichotomy of thiocyanate-involving noncovalent
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …

Enolonium species/iodo (III) enolates of carbonyl compounds have been suggested to be
intermediates in a wide variety of hypervalent iodine induced chemical transformations of …