Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Ligand‐to‐metal charge transfer (LMCT) photochemistry at 3d‐metal complexes: an emerging tool for sustainable organic synthesis

F Juliá - ChemCatChem, 2022 - Wiley Online Library
Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

Visible‐light‐induced homolysis of earth‐abundant metal‐substrate complexes: A complementary activation strategy in photoredox catalysis

Y Abderrazak, A Bhattacharyya… - Angewandte Chemie …, 2021 - Wiley Online Library
The mainstream applications of visible‐light photoredox catalysis predominately involve
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …

Transition metal-catalyzed organic reactions under visible light: recent developments and future perspectives

WM Cheng, R Shang - ACS Catalysis, 2020 - ACS Publications
The development of transition metal (TM) catalysis for organic synthesis under visible light
without recourse to typical photoredox catalysts has become a rapidly growing area of …

Energy transfer catalysis mediated by visible light: principles, applications, directions

F Strieth-Kalthoff, MJ James, M Teders… - Chemical Society …, 2018 - pubs.rsc.org
Harnessing visible light to access excited (triplet) states of organic compounds can enable
impressive reactivity modes. This tutorial review covers the photophysical fundamentals and …

The mechanism of visible light-induced C–C cross-coupling by C sp3–H bond activation

B Maity, S Dutta, L Cavallo - Chemical Society Reviews, 2023 - pubs.rsc.org
Csp3–C cross-coupling by activating Csp3–H bonds is a dream reaction for the chemical
community, and visible light-induced transition metal-catalysis under mild reaction …

Mechanisms of nickel-catalyzed cross-coupling reactions

JB Diccianni, T Diao - Trends in Chemistry, 2019 - cell.com
Advances in nickel-catalyzed cross-coupling reactions have expanded the chemical space
of accessible structures and enabled new synthetic disconnections. The unique properties of …

A toolbox approach to construct broadly applicable metal-free catalysts for photoredox chemistry: deliberate tuning of redox potentials and importance of halogens in …

E Speckmeier, TG Fischer, K Zeitler - Journal of the American …, 2018 - ACS Publications
The targeted choice of specific photocatalysts has been shown to play a critical role for the
successful realization of challenging photoredox catalytic transformations. Herein, we …

Photoactive complexes with earth-abundant metals

OS Wenger - Journal of the American Chemical Society, 2018 - ACS Publications
In this invited Perspective, recent developments and possible future directions of research
on photoactive coordination compounds made from nonprecious transition metal elements …