On the basis of its generally accessible I/II redox couple and bioavailability, copper plays a
wide variety of roles in nature that mostly involve electron transfer (ET), O 2 binding …

The two-electron oxidation of primary alcohols with dioxygen to yield aldehyde and
hydrogen peroxide that is catalyzed by galactose oxidase (GAO) occurs at an intriguing …

The tetradentate ligand N, N '-bis (3, 5-di-tert-butyl-2-hydroxyphenyl)-1, 2-
phenylenediamine, H4L1, has been prepared, and its square planar complexes [CuII (L3)] …

Two reaction pathways are catalyzed by the dinuclear copper (ii)–phenoxyl complex 1—a
functional model for the metalloenzyme galactose oxidase—by the oxidation of primary and …

The physical organic chemistry and spectroscopic features of the ligand phenoxyl are
reviewed. Some well‐characterized metalloproteins known to contain tyrosyl radicals are …

In the last decade, we have experienced massive progress in spectroscopic methods for
mass-selected ions. The aim of this tutorial review is to present action spectroscopy as a …

The controlled oxidation of C–H bonds is one of the most challenging and difficult reactions
in organic chemistry. Generally, it requires either stoichiometric amounts of toxic heavy metal …

One-Electron Oxidized Nickel(II)−(Disalicylidene)diamine Complex: Temperature-Dependent
Tautomerism between Ni(III)−Phenolate and Ni(II)−Phenoxyl Radical States | Journal of the …

The geometric and electronic structure of an oxidized Cu complex ([Cu Sal]+; Sal= N, N′-
bis (3, 5-di-tert-butylsalicylidene)-1, 2-cyclohexane-(1 R, 2 R)-diamine) with a non-innocent …

Group 10 metal (II) complexes of H2tbu-salen (H2tbu-salen= N, N '-bis (3 ', 5 '-di-tert-
butylsalicylidene) ethylenediamine) and H2tbu-salcn (H2tbu-salcn= N, N '-bis (3 ', 5 '-di-tert …