Recent advances in Mn‐rich layered materials for sodium‐ion batteries

K Wang, H Zhuo, J Wang, F Poon… - Advanced Functional …, 2023‏ - Wiley Online Library
Branded with low cost and a high degree of safety, with an ambitious aim of substituting
lithium‐ion batteries in many fields, sodium‐ion batteries have received fervid attention in …

Layered oxide cathodes for sodium-ion batteries: microstructure design, local chemistry and structural unit

LY Kong, HX Liu, YF Zhu, JY Li, Y Su, HW Li… - Science China …, 2024‏ - Springer
Because of the low price and abundant reserves of sodium compared with lithium, the
research of sodium-ion batteries (SIBs) in the field of large-scale energy storage has …

Delocalized electron holes on oxygen in a battery cathode

RA House, GJ Rees, K McColl, JJ Marie… - Nature Energy, 2023‏ - nature.com
Oxide ions in transition metal oxide cathodes can store charge at high voltage offering a
route towards higher energy density batteries. However, upon charging these cathodes, the …

Prospective sustainability screening of sodium‐ion battery cathode materials

M Baumann, M Häringer, M Schmidt… - Advanced Energy …, 2022‏ - Wiley Online Library
Sodium‐ion batteries (SIB) are considered as a promising alternative to overcome existing
sustainability challenges related to Lithium‐ion batteries (LIB), such as the use of critical and …

A universal interfacial reconstruction strategy based on converting residual alkali for sodium layered oxide cathodes: marvelous air stability, reversible anion redox …

LY Kong, JY Li, HX Liu, YF Zhu, J Wang… - Journal of the …, 2024‏ - ACS Publications
Mn-based layered oxide cathodes have attracted widespread attention due to high capacity
and low cost, however, poor air stability, irreversible phase transitions, and slow kinetics …

Lithium orbital hybridization chemistry to stimulate oxygen redox with reversible phase evolution in sodium-layered oxide cathodes

H Dong, H Liu, YJ Guo, YH Feng, X Zhu… - Journal of the …, 2024‏ - ACS Publications
Searching for high energy-density electrode materials for sodium ion batteries has revealed
Na-deficient intercalation compounds with lattice oxygen redox as promising high-capacity …

Enhancing the reversibility of lattice oxygen redox through modulated transition metal–oxygen covalency for layered battery electrodes

C Cheng, C Chen, S Chu, H Hu, T Yan, X **a… - Advanced …, 2022‏ - Wiley Online Library
Utilizing reversible lattice oxygen redox (OR) in battery electrodes is an essential strategy to
overcome the capacity limitation set by conventional transition metal redox. However, lattice …

NaMn0. 2Fe0. 2Co0. 2Ni0. 2Ti0. 2O2 high-entropy layered oxide–experimental and theoretical evidence of high electrochemical performance in sodium batteries

K Walczak, A Plewa, C Ghica, W Zając… - Energy Storage …, 2022‏ - Elsevier
Li-ion batteries, widely used in portable electronics, electric vehicles, and energy storage
systems, are an integral element of our daily life. However, the limitation of lithium sources …

Earth‐Abundant Na‐Mg‐Fe‐Mn‐O cathode with reversible hybrid anionic and cationic redox

Y Niu, Z Hu, B Zhang, D **ao, H Mao… - Advanced Energy …, 2023‏ - Wiley Online Library
Na‐ion batteries (NIBs) are promising for grid‐scale energy storage applications. However,
the lack of Co, Ni‐free cathode materials has made them less cost‐effective. In this work …

Transition metal migration and O2 formation underpin voltage hysteresis in oxygen-redox disordered rocksalt cathodes

K McColl, RA House, GJ Rees, AG Squires… - Nature …, 2022‏ - nature.com
Lithium-rich disordered rocksalt cathodes display high capacities arising from redox
chemistry on both transition-metal ions (TM-redox) and oxygen ions (O-redox), making them …