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Pushing the limits of acene chemistry: The recent surge of large acenes
C Tönshoff, HF Bettinger - Chemistry–A European Journal, 2021 - Wiley Online Library
Acenes, consisting of linearly fused benzene rings, are an important fundamental class of
organic compounds with various applications. Hexacene is the largest acene that was …
organic compounds with various applications. Hexacene is the largest acene that was …
Unusual stabilization of larger acenes and heteroacenes
The larger acenes and heteroacenes (> pentacenes) are attractive, yet sensitive materials;
several strategies were developed to stabilize such species.“Classic” approaches employ …
several strategies were developed to stabilize such species.“Classic” approaches employ …
Recent highlights and perspectives on acene based molecules and materials
Q Ye, C Chi - Chemistry of Materials, 2014 - ACS Publications
Acenes represent a series of molecules with intriguing physical and chemical properties for
applications in organic electronics. Nevertheless, the stability and solubility issues …
applications in organic electronics. Nevertheless, the stability and solubility issues …
Evolution of the optical gap in the acene series: undecacene
B Shen, J Tatchen, E Sanchez‐Garcia… - Angewandte …, 2018 - Wiley Online Library
Undecacene, the largest member of the acene family, was photogenerated in a polymer
matrix under cryogenic conditions from a precursor with two α‐diketone bridges. The …
matrix under cryogenic conditions from a precursor with two α‐diketone bridges. The …
Heptacene: characterization in solution, in the solid state, and in films
R Einholz, T Fang, R Berger… - Journal of the …, 2017 - ACS Publications
Acenes comprise an important class of organic semiconducting materials. As graphene
nanoribbons of ultimate width, they are valuable atom-precise model systems for studying …
nanoribbons of ultimate width, they are valuable atom-precise model systems for studying …
[HTML][HTML] Photochemistry of various acene based molecules
Photochemistry based on acenes and their derivatives is one of the emerging research
areas in the field of polycyclic aromatic hydrocarbons (PAHs). However, due to the …
areas in the field of polycyclic aromatic hydrocarbons (PAHs). However, due to the …
Strategies for the synthesis of higher acenes
The outstanding performance of pentacene‐based molecules in molecular electronics, as
well as the predicted enhanced semiconducting properties of extended acenes, have …
well as the predicted enhanced semiconducting properties of extended acenes, have …
BODIPYs with photoactivatable fluorescence
The borondipyrromethene (BODIPY) chromophore is a versatile platform for the construction
of photoresponsive dyes with unique properties. Specifically, its covalent connection to a …
of photoresponsive dyes with unique properties. Specifically, its covalent connection to a …
Synthesis and morphological control of organic semiconducting materials using the precursor approach
Pristine π-extended aromatic compounds are attractive as organic functional materials
including organic semiconductors, but are difficult to synthesize in pure form because of their …
including organic semiconductors, but are difficult to synthesize in pure form because of their …
The longest acenes
HF Bettinger, C Tönshoff - The Chemical Record, 2015 - Wiley Online Library
For a long time, the largest known member of the acene series was hexacene, consisting of
six linearly fused benzene rings. The next higher member, heptacene, is so highly reactive …
six linearly fused benzene rings. The next higher member, heptacene, is so highly reactive …