Thiomethyltetrazines Are Reversible Covalent Cysteine Warheads Whose Dynamic Behavior can be “Switched Off” via Bioorthogonal Chemistry Inside Live Cells

AM Tallon, Y Xu, GM West, CW Am Ende… - Journal of the American …, 2023 - ACS Publications
Electrophilic small molecules that can reversibly modify proteins are of growing interest in
drug discovery. However, the ability to study reversible covalent probes in live cells can be …

One-pot method for preparing DNA, RNA, and protein for multiomics analysis

S Biedka, D Alkam, CL Washam, S Yablonska… - Communications …, 2024 - nature.com
Typical multiomics studies employ separate methods for DNA, RNA, and protein sample
preparation, which is labor intensive, costly, and prone to sampling bias. We describe a …

IP-to-MS: An Unbiased Workflow for Antigen Profiling

S Biedka, S Yablonska, X Peng, D Alkam… - Journal of Proteome …, 2025 - ACS Publications
Immunoprecipitation is among the most widely utilized methods in biomedical research, with
applications that include the identification of antibody targets and associated proteins. The …

Influence of Aldehyde Dehydrogenase Inhibition on Stemness of Endometrial Cancer Stem Cells

B Serambeque, C Mestre, G Correia-Barros, R Teixo… - Cancers, 2024 - mdpi.com
Simple Summary Cancer stem cells (CSCs) are responsible for tumour initiation, growth,
dissemination, and resistance to therapy. In this study, we intended to evaluate the effect of …

Expanding Glycomic Investigations through Thiol-Derivatized Glycans

RD Hurst, A Nieves, M Brichacek - Molecules, 2023 - mdpi.com
N-(2-thioethyl)-2-aminobenzamide (TEAB), a novel glycan auxiliary, was synthesized and its
utility was evaluated. The auxiliary was conjugated to glycans by reductive amination with …

Affinity Bioorthogonal Chemistry (ABC) Tags for Site‐Selective Conjugation, On‐Resin Protein‐Protein Coupling, and Purification of Protein Conjugates

SL Scinto, TR Reagle, JM Fox - … Chemie International Edition, 2022 - Wiley Online Library
The site‐selective functionalization of proteins has broad application in chemical biology,
but can be limited when mixtures result from incomplete conversion or the formation of …

Affinity Bioorthogonal Chemistry (ABC) Tags for Site-selective Conjugation, On-resin Protein-Protein Coupling, and Purification of Protein Conjugates

J Fox, S Scinto, T Reagle - 2022 - chemrxiv.org
The site-selective functionalization of proteins has broad application in chemical biology, but
can be limited when mixtures result from incomplete conversion or the formation of protein …

[PDF][PDF] MT-Trypsin mediated rapid in-gel digestion with trypsin removal

S Yablonska, S Biedka, JS Minden - impactproteomics.com
Utilizing click chemistry technology, we developed an in-gel digestion protocol that enables
rapid, twohour enzymatic digestion of proteins. This workflow includes aspects of a …