Gold-catalyzed carbon− heteroatom bond-forming reactions

A Corma, A Leyva-Pérez, MJ Sabater - Chemical reviews, 2011 - ACS Publications
After the long-held assumption of the unreactivity of gold, numerous reactions catalyzed by
this noble metal have been increasingly emerging in the literature over the past 2 decades …

Effect of oxygen functional groups on competitive adsorption of benzene and water on carbon materials: Density functional theory study

H Zhao, Z Tang, M He, X Yang, S Lai, K An… - Science of The Total …, 2023 - Elsevier
It is important to study the effect of oxygen-containing functional groups on the competitive
adsorption mechanism of benzene and water on the surface of carbon materials, and to …

Hydrophenoxylation of alkynes by gold catalysts: a mini review

M Ramos, M Solà, A Poater - Journal of Molecular Modeling, 2024 - Springer
Context The field of chemistry has significantly evolved, with catalysis playing a crucial role
in transforming chemical processes. From Valerius' use of sulfuric acid in the sixteenth …

Quantitative simulationSimulation of nitrogen do** effects on benzene selective adsorption by activated carbon in aqueous conditions

H Zhao, Z Tang, Z Wang, J Li, Z Hu, Q Wang, Q Yu… - Environmental …, 2024 - Elsevier
Investigating the impact of nitrogen do** on the selective adsorption of benzene on
activated carbon under aqueous conditions holds significant importance in regulating …

Gold (I)–NHC complexes of antitumoral diarylimidazoles: Structures, cellular uptake routes and anticancer activities

L Kaps, B Biersack, H Müller-Bunz, K Mahal… - Journal of Inorganic …, 2012 - Elsevier
Five new heterocyclic gold carbene complexes were prepared, four chlorido-[1, 3-dimethyl-
4, 5-diarylimidazol-2-ylidene] gold complexes 6a-d and a chlorido-[1, 3-dibenzylimidazol-2 …

Oxidant-Free Au(I)-Catalyzed Halide Exchange and Csp2–O Bond Forming Reactions

J Serra, CJ Whiteoak, F Acuña-Parés… - Journal of the …, 2015 - ACS Publications
Au has been demonstrated to mediate a number of organic transformations through the
utilization of its π Lewis acid character, Au (I)/Au (III) redox properties or a combination of …

Construction of Heterobimetallic Catalytic Scaffold with a Carbene-Bipyridine Ligand: Gold–Zinc Two-Metal Catalysis for Intermolecular Addition of O-Nucleophiles to …

VK Rawat, K Higashida, M Sawamura - ACS catalysis, 2022 - ACS Publications
A gold (I) complex bearing an imidazo [1, 5-a] pyridin-3-ylidene ligand with a 2, 2′-
bipyridine moiety at the C5 position was prepared as a template for constructing …

The importance of hydrogen bonding to stereoselectivity and catalyst turnover in gold-catalyzed cyclization of monoallylic diols

T Ghebreghiorgis, B Biannic, BH Kirk… - Journal of the …, 2012 - ACS Publications
Density functional calculations and experiment were used to examine the mechanism,
reactivity, and origin of chirality transfer in monophosphine Au-catalyzed monoallylic diol …

Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes

P Arnaut, NB Pozsoni, F Nahra, NV Tzouras… - Dalton …, 2024 - pubs.rsc.org
We disclose a novel series of N-heterocyclic carbene (NHC) gold complexes with varied
steric and electronic properties, bearing fluorinated alkoxide anions. Early reactivity studies …

Gold (I)− Catalyzed Synthesis of Cyclic Sulfamides via an Intramolecular Dehydrative Amination of Allylic Alcohols: A Strategy for 1, 3‐Diamine Synthesis

S Lee, DM Kim, JS Ryu - Advanced Synthesis & Catalysis, 2024 - Wiley Online Library
A gold (I)‐catalyzed intramolecular dehydrative amination method has been developed to
synthesize diverse cyclic sulfamides efficiently. Reactions proceed smoothly at room …