Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges
IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
A fruitful decade of organofluorine chemistry: new reagents and reactions
FL Qing, XY Liu, JA Ma, Q Shen, Q Song… - CCS …, 2022 - chinesechemsoc.org
The development of synthetic methods for the introduction of the fluorine atom and
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …
Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups
Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …
strategies that is currently attracting tremendous attention with the aim to provide alternative …
Recent advances in C–S bond formation via C–H bond functionalization and decarboxylation
The development of mild and general methods for C–S bond formation has received
significant attention because the C–S bond is indispensable in many important biological …
significant attention because the C–S bond is indispensable in many important biological …
Shelf-stable electrophilic reagents for trifluoromethylthiolation
Conspectus Fluorine, which is the most electronegative element and has a small atomic
radius, plays a key role in pharmaceutical, agrochemical, and materials sciences. One of the …
radius, plays a key role in pharmaceutical, agrochemical, and materials sciences. One of the …
Visible-Light-Promoted Activation of Unactivated C(sp3)–H Bonds and Their Selective Trifluoromethylthiolation
S Mukherjee, B Maji, A Tlahuext-Aca… - Journal of the American …, 2016 - ACS Publications
Selective functionalization of ubiquitous C (sp3)–H bonds using visible light is a highly
challenging yet desirable goal in organic synthesis. The development of such processes …
challenging yet desirable goal in organic synthesis. The development of such processes …
Fundamental studies and development of nickel-catalyzed trifluoromethylthiolation of aryl chlorides: active catalytic species and key roles of ligand and traceless …
A catalytic protocol to convert aryl and heteroaryl chlorides to the corresponding
trifluoromethyl sulfides is reported herein. It relies on a relatively inexpensive Ni (cod) 2/dppf …
trifluoromethyl sulfides is reported herein. It relies on a relatively inexpensive Ni (cod) 2/dppf …
Visible light‐induced C− H bond functionalization: a critical review
L Revathi, L Ravindar, WY Fang… - Advanced Synthesis …, 2018 - Wiley Online Library
In recent years, visible‐light‐induced C− H bond functionalization has become an emerging
field at the forefront of organic chemistry. In a general sense, these approaches rely on the …
field at the forefront of organic chemistry. In a general sense, these approaches rely on the …
Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of C H Bond Functionalization
The direct introduction of fluorine and fluorinated building blocks has recently attracted a lot
of attention and particularly the direct functionalization of alkenes and alkynes. This review …
of attention and particularly the direct functionalization of alkenes and alkynes. This review …
Recent developments in palladium-catalyzed C–S bond formation
J Li, S Yang, W Wu, H Jiang - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Transition metal-catalyzed C–S bond formation reactions have attracted considerable
attention in the recent years. In this regard, palladium-catalyzed C–S bond formation is …
attention in the recent years. In this regard, palladium-catalyzed C–S bond formation is …