Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

A fruitful decade of organofluorine chemistry: new reagents and reactions

FL Qing, XY Liu, JA Ma, Q Shen, Q Song… - CCS …, 2022 - chinesechemsoc.org
The development of synthetic methods for the introduction of the fluorine atom and
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Recent advances in C–S bond formation via C–H bond functionalization and decarboxylation

C Shen, P Zhang, Q Sun, S Bai, TSA Hor… - Chemical Society …, 2015 - pubs.rsc.org
The development of mild and general methods for C–S bond formation has received
significant attention because the C–S bond is indispensable in many important biological …

Shelf-stable electrophilic reagents for trifluoromethylthiolation

X Shao, C Xu, L Lu, Q Shen - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Fluorine, which is the most electronegative element and has a small atomic
radius, plays a key role in pharmaceutical, agrochemical, and materials sciences. One of the …

Visible-Light-Promoted Activation of Unactivated C(sp3)–H Bonds and Their Selective Trifluoromethylthiolation

S Mukherjee, B Maji, A Tlahuext-Aca… - Journal of the American …, 2016 - ACS Publications
Selective functionalization of ubiquitous C (sp3)–H bonds using visible light is a highly
challenging yet desirable goal in organic synthesis. The development of such processes …

Fundamental studies and development of nickel-catalyzed trifluoromethylthiolation of aryl chlorides: active catalytic species and key roles of ligand and traceless …

G Yin, I Kalvet, U Englert… - Journal of the American …, 2015 - ACS Publications
A catalytic protocol to convert aryl and heteroaryl chlorides to the corresponding
trifluoromethyl sulfides is reported herein. It relies on a relatively inexpensive Ni (cod) 2/dppf …

Visible light‐induced C− H bond functionalization: a critical review

L Revathi, L Ravindar, WY Fang… - Advanced Synthesis …, 2018 - Wiley Online Library
In recent years, visible‐light‐induced C− H bond functionalization has become an emerging
field at the forefront of organic chemistry. In a general sense, these approaches rely on the …

Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of C H Bond Functionalization

T Besset, T Poisson… - Chemistry–A European …, 2014 - Wiley Online Library
The direct introduction of fluorine and fluorinated building blocks has recently attracted a lot
of attention and particularly the direct functionalization of alkenes and alkynes. This review …

Recent developments in palladium-catalyzed C–S bond formation

J Li, S Yang, W Wu, H Jiang - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Transition metal-catalyzed C–S bond formation reactions have attracted considerable
attention in the recent years. In this regard, palladium-catalyzed C–S bond formation is …