Coherent state based solutions of the time-dependent Schrödinger equation: hierarchy of approximations to the variational principle

M Werther, SL Choudhury… - International Reviews in …, 2021 - Taylor & Francis
In this review, we give a comprehensive comparison of the most widely used coherent state
(CS) based methods to solve the time-dependent Schrödinger equation (TDSE). Starting …

[HTML][HTML] Ultrafast hole deformation revealed by molecular attosecond interferometry

Y Huang, J Zhao, Z Shu, Y Zhu, J Liu, W Dong… - Ultrafast …, 2021 - spj.science.org
Understanding the evolution of molecular electronic structures is the key to explore and
control photochemical reactions and photobiological processes. Subjected to strong laser …

Map** electronic decoherence pathways in molecules

I Gustin, CW Kim, DW McCamant… - Proceedings of the …, 2023 - National Acad Sciences
Establishing the fundamental chemical principles that govern molecular electronic quantum
decoherence has remained an outstanding challenge. Fundamental questions such as how …

Decoherence and revival in attosecond charge migration driven by non-adiabatic dynamics

DT Matselyukh, V Despré, NV Golubev, AI Kuleff… - Nature physics, 2022 - nature.com
Attosecond charge migration is a periodic evolution of the charge density at specific sites of
a molecule on a timescale defined by the energy intervals between the electronic states …

Applicability of the thawed Gaussian wavepacket dynamics to the calculation of vibronic spectra of molecules with double-well potential energy surfaces

T Begusic, E Tapavicza, J Vanicek - Journal of Chemical Theory …, 2022 - ACS Publications
Simulating vibrationally resolved electronic spectra of anharmonic systems, especially those
involving double-well potential energy surfaces, often requires expensive quantum …

Electronic Coherences in Molecules: The Projected Nuclear Quantum Momentum as a Hidden Agent

EV Arribas, NT Maitra - Physical review letters, 2024 - APS
Electronic coherences are key to understanding and controlling photoinduced molecular
transformations. We identify a crucial quantum-mechanical feature of electron-nuclear …

[HTML][HTML] On-the-fly ab initio semiclassical evaluation of third-order response functions for two-dimensional electronic spectroscopy

T Begušić, J Vaníček - The Journal of Chemical Physics, 2020 - pubs.aip.org
Ab initio computation of two-dimensional electronic spectra is an expanding field, whose
goal is improving upon simple, few-dimensional models often employed to explain …

Reducing the cost of TD-CI simulations of strong field ionization

AS Durden, HB Schlegel - The Journal of Physical Chemistry A, 2024 - ACS Publications
Strong field ionization of molecules by intense laser pulses can be simulated by time-
dependent configuration interaction (TD-CI) with a complex absorbing potential (CAP) …

Core-valence attosecond transient absorption spectroscopy of polyatomic molecules

NV Golubev, J Vaníček, AI Kuleff - Physical Review Letters, 2021 - APS
Tracing ultrafast processes induced by interaction of light with matter is often very
challenging. In molecular systems, the initially created electronic coherence becomes …

High-order geometric integrators for the local cubic variational Gaussian wavepacket dynamics

R Moghaddasi Fereidani, JJL Vaníček - The Journal of Chemical …, 2024 - pubs.aip.org
Gaussian wavepacket dynamics has proven to be a useful semiclassical approximation for
quantum simulations of high-dimensional systems with low anharmonicity. Compared to …