Physicochemical concepts of the lithium metal anode in solid-state batteries

T Krauskopf, FH Richter, WG Zeier, J Janek - Chemical reviews, 2020 - ACS Publications
Develo** reversible lithium metal anodes with high rate capability is one of the central
aims of current battery research. Lithium metal anodes are not only required for the …

Electrochemical impedance spectroscopy for all‐solid‐state batteries: theory, methods and future outlook

P Vadhva, J Hu, MJ Johnson, R Stocker… - …, 2021 - Wiley Online Library
Electrochemical impedance spectroscopy (EIS) is widely used to probe the physical and
chemical processes in lithium (Li)‐ion batteries (LiBs). The key parameters include state‐of …

Rechargeable alkali-ion battery materials: theory and computation

A Van der Ven, Z Deng, S Banerjee, SP Ong - Chemical reviews, 2020 - ACS Publications
Since its development in the 1970s, the rechargeable alkali-ion battery has proven to be a
truly transformative technology, providing portable energy storage for devices ranging from …

Designing all-solid-state batteries by theoretical computation: a review

S Zhang, J Ma, S Dong, G Cui - Electrochemical Energy Reviews, 2023 - Springer
All-solid-state batteries (ASSBs) with solid-state electrolytes and lithium-metal anodes have
been regarded as a promising battery technology to alleviate range anxiety and address …

Synergistically Engineering Grains and Grain Boundaries toward Li Dendrite-Free Li7La3Zr2O12

S Deng, H Zhu, Z Zheng, Z Kong, Z Wang, W Zhou… - Nano Letters, 2024 - ACS Publications
Cation-doped cubic Li7La3Zr2O12 is regarded as a promising solid electrolyte for safe and
energy-dense solid-state lithium batteries. However, it suffers from the formation of Li2CO3 …

Devil is in the defects: electronic conductivity in solid electrolytes

P Gorai, T Famprikis, B Singh, V Stevanovic… - Chemistry of …, 2021 - ACS Publications
Rechargeable solid-state batteries (SSBs) continue to gain prominence due to their
increased safety. However, a number of outstanding challenges still prevent their adoption …

Excellent Stability of Ga-Doped Garnet Electrolyte against Li Metal Anode via Eliminating LiGaO2 Precipitates for Advanced All-Solid-State Batteries

J Li, H Luo, K Liu, J Zhang, H Zhai, X Su… - … Applied Materials & …, 2023 - ACS Publications
Ga-doped garnet-type Li7La3Zr2O12 (Ga-LLZO) ceramics have long been recognized as
ideal electrolyte candidates for all-solid-state lithium batteries (ASSLBs). However, in this …

Cation disorder dominates the defect chemistry of high-voltage LiMn 1.5 Ni 0.5 O 4 (LMNO) spinel cathodes

J Cen, B Zhu, SR Kavanagh, AG Squires… - Journal of Materials …, 2023 - pubs.rsc.org
High-voltage spinel LiMn1. 5Ni0. 5O4 (LMNO) can exist in a Mn/Ni ordered P4332 or
disordered Fdm arrangement with a majority of literature studies reporting improved …

Mechanistic Origin of Superionic Lithium Diffusion in Anion-Disordered Li6PS5X Argyrodites

BJ Morgan - Chemistry of Materials, 2021 - ACS Publications
The rational development of fast-ion-conducting solid electrolytes for all-solid-state lithium-
ion batteries requires understanding the key structural and chemical principles that give …

Polaron-Based Electronic Conduction in Mixed Ionic-Electronic Conducting Lithium Garnets

CE Schwarz, RS Saravanan, NM Borodin… - ACS Energy …, 2024 - ACS Publications
Recent research has demonstrated that doped lithium garnet compositions with mixed ionic–
electronic conducting (MIEC) properties can significantly enhance the performance of solid …