Supramolecular‐macrocycle‐based crystalline organic materials
Supramolecular macrocycles are well known as guest receptors in supramolecular
chemistry, especially host− guest chemistry. In addition to their wide applications in host …
chemistry, especially host− guest chemistry. In addition to their wide applications in host …
Recent advances in the syntheses and properties of polynitrogen pentazolate anion cyclo-N 5− and its derivatives
P Wang, Y Xu, Q Lin, M Lu - Chemical Society Reviews, 2018 - pubs.rsc.org
The pentazolate anion, or cyclo-N5−, which is a five-membered ring composed solely of
nitrogen atoms, has a unique structure among polynitrogen compounds. Cyclo-N5− is …
nitrogen atoms, has a unique structure among polynitrogen compounds. Cyclo-N5− is …
Synthesis and Characterization of cyclo-Pentazolate Salts of NH4+, NH3OH+, N2H5+, C(NH2)3+, and N(CH3)4+
C Yang, C Zhang, Z Zheng, C Jiang, J Luo… - Journal of the …, 2018 - ACS Publications
A breakthrough in polynitrogen chemistry was recently achieved by our bulk synthesis of
(N5) 6 (H3O) 3 (NH4) 4Cl in which the cyclo-pentazolate anions were stabilized extensively …
(N5) 6 (H3O) 3 (NH4) 4Cl in which the cyclo-pentazolate anions were stabilized extensively …
Predictions on high-power trivalent metal pentazolate salts
High-energy-density materials (HEDMs) have been intensively studied for their significance
in fundamental sciences and practical applications. Here, using the molecular crystal …
in fundamental sciences and practical applications. Here, using the molecular crystal …
Linker substituents control the thermodynamic stability in metal–organic frameworks
We report the first systematic experimental and theoretical study of the relationship between
the linker functionalization and the thermodynamic stability of metal–organic frameworks …
the linker functionalization and the thermodynamic stability of metal–organic frameworks …
Pressure-stabilized high-energy-density alkaline-earth-metal pentazolate salts
Polynitrogen compounds especially pentazolate anion complexes recently have attracted
substantial attention due to their promising potential as high-energy-density materials. Here …
substantial attention due to their promising potential as high-energy-density materials. Here …
Prediction of stable iron nitrides at ambient and high pressures with progressive formation of new polynitrogen species
Nitride materials are of considerable interest due to their fundamental importance and
practical applications. However, synthesis of transition metal nitrides often requires extreme …
practical applications. However, synthesis of transition metal nitrides often requires extreme …
Review of the current synthesis and properties of energetic pentazolate and derivatives thereof
DR Wozniak, DG Piercey - Engineering, 2020 - Elsevier
The latest member of the azole family, the pentazolate or cyclo-N 5−, has received increased
attention since its first mass-spectral detection by Christe et al. in 2002. As it is carbon-and …
attention since its first mass-spectral detection by Christe et al. in 2002. As it is carbon-and …
A promising hydrogen peroxide adduct of ammonium cyclopentazolate as a green propellant component
A novel H2O2 adduct of ammonium cyclopentazolate, NH4N5· ½H2O2, was readily
synthesized by a simple and effective method. This adduct, as determined by single-crystal …
synthesized by a simple and effective method. This adduct, as determined by single-crystal …
High‐Pressure Synthesis of Metal–Inorganic Frameworks Hf4N20⋅N2, WN8⋅N2, and Os5N28⋅3 N2 with Polymeric Nitrogen Linkers
Polynitrides are intrinsically thermodynamically unstable at ambient conditions and require
peculiar synthetic approaches. Now, a one‐step synthesis of metal–inorganic frameworks …
peculiar synthetic approaches. Now, a one‐step synthesis of metal–inorganic frameworks …