Single electron transfer in radical ion and radical-mediated organic, materials and polymer synthesis

N Zhang, SR Samanta, BM Rosen, V Percec - Chemical Reviews, 2014 - ACS Publications
The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one …

Organocobalt complexes as sources of carbon-centered radicals for organic and polymer chemistries

J Demarteau, A Debuigne, C Detrembleur - Chemical reviews, 2019 - ACS Publications
Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …

Overview of cobalt-mediated radical polymerization: Roots, state of the art and future prospects

A Debuigne, R Poli, C Jérôme, R Jérôme… - Progress in Polymer …, 2009 - Elsevier
Controlled radical polymerization (CRP) techniques offer the opportunity to properly design
polymer chains and adjust their chemical and physical properties. Among these techniques …

Polyacrylonitrile-derived nanostructured carbon materials

M Kopeć, M Lamson, R Yuan, C Tang, M Kruk… - Progress in Polymer …, 2019 - Elsevier
An overview on polyacrylonitrile (PAN)-derived carbon nanomaterials is presented.
Controlled synthesis of well-defined PAN by reversible deactivation radical polymerization …

Poly(N‐vinylcaprolactam): A Thermoresponsive Macromolecule with Promising Future in Biomedical Field

J Liu, A Debuigne, C Detrembleur… - Advanced healthcare …, 2014 - Wiley Online Library
Poly (N‐vinylcaprolactam)(PNVCL) is a thermoresponsive and biocompatible polymer that
raises an increasing interest in the biomedical area, especially in drug delivery systems …

Organometallic mediated radical polymerization

LEN Allan, MR Perry, MP Shaver - Progress in polymer science, 2012 - Elsevier
Controlled radical polymerization has become increasingly important over the past decade
and a half, allowing for the facile synthesis of specific macromolecular architectures with …

Precision design of ethylene-and polar-monomer-based copolymers by organometallic-mediated radical polymerization

A Kermagoret, A Debuigne, C Jérôme… - Nature Chemistry, 2014 - nature.com
The copolymerization of ethylene with polar monomers is a major challenge when it comes
to the manufacture of materials with potential for a wide range of commercial applications. In …

Insight into organometallic-mediated radical polymerization

M Hurtgen, C Detrembleur, C Jerome… - Polymer Reviews, 2011 - Taylor & Francis
This review focuses on an emerging class of controlled radical polymerization named
Organometallic-Mediated Radical Polymerization (OMRP). The latter is based on the …

Organometallic‐mediated radical polymerization of vinylidene fluoride

S Banerjee, V Ladmiral, A Debuigne… - Angewandte Chemie …, 2018 - Wiley Online Library
An unprecedented level of control for the radical polymerization of vinylidene fluoride (VDF),
yielding well‐defined PVDF (at least up to 14 500 g mol− 1) with low dispersity (≤ 1.32) …

Modern trends in controlled synthesis of functional polymers: fundamental aspects and practical applications

DF Grishin, ID Grishin - Russian Chemical Reviews, 2021 - iopscience.iop.org
Major trends in controlled radical polymerization (CRP) or reversible-deactivation radical
polymerization (RDRP), the most efficient method of synthesis of well-defined homo-and …