Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R **, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R ** - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J **e - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Metal Single‐Atom Cocatalyst on Carbon Nitride for the Photocatalytic Hydrogen Evolution Reaction: Effects of Metal Species

Y Akinaga, T Kawawaki, H Kameko… - Advanced Functional …, 2023 - Wiley Online Library
Single‐atom (SA) catalysts exhibit high activity in various reactions because there are no
inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields …

Shining photocatalysis by gold-based nanomaterials

H Zhu, X Yuan, Q Yao, J **e - Nano Energy, 2021 - Elsevier
As an environmentally friendly technology, photocatalysis has been widely used in many
fields. Currently, the drawbacks of pristine semiconductors as traditional photocatalysts …

Atomically precise thiolate-protected gold nanoclusters: current advances in solar-powered photoredox catalysis

H Liang, Q Chen, QL Mo, Y Wu, FX **ao - Journal of Materials …, 2023 - pubs.rsc.org
Photocatalysis has been regarded as an emerging technology to convert renewable solar
energy to chemical fuels, providing unprecedented opportunities for solving the deteriorating …

Creation of High‐Performance Heterogeneous Photocatalysts by Controlling Ligand Desorption and Particle Size of Gold Nanocluster

T Kawawaki, Y Kataoka, M Hirata… - Angewandte Chemie …, 2021 - Wiley Online Library
Recently, the creation of new heterogeneous catalysts using the unique electronic/geometric
structures of small metal nanoclusters (NCs) has received considerable attention. However …

Thiolate‐protected metal nanoclusters: recent development in synthesis, understanding of reaction, and application in energy and environmental field

T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …

Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties

S Hossain, D Hirayama, A Ikeda, M Ishimi… - …, 2023 - Wiley Online Library
Thiolate (SR)‐protected gold nanoclusters (Aun (SR) m NCs) are a rare type of material
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …