Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …
achieving a fundamental understanding on the nature of the active sites in bimetallic …
Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …
occupy an important position. Unfortunately, no two nanoparticles from conventional …
Atomically precise alloy nanoclusters: syntheses, structures, and properties
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …
providing unique opportunities for investigating the quantum effects and precise structure …
Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …
Metal Single‐Atom Cocatalyst on Carbon Nitride for the Photocatalytic Hydrogen Evolution Reaction: Effects of Metal Species
Y Akinaga, T Kawawaki, H Kameko… - Advanced Functional …, 2023 - Wiley Online Library
Single‐atom (SA) catalysts exhibit high activity in various reactions because there are no
inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields …
inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields …
Shining photocatalysis by gold-based nanomaterials
As an environmentally friendly technology, photocatalysis has been widely used in many
fields. Currently, the drawbacks of pristine semiconductors as traditional photocatalysts …
fields. Currently, the drawbacks of pristine semiconductors as traditional photocatalysts …
Atomically precise thiolate-protected gold nanoclusters: current advances in solar-powered photoredox catalysis
H Liang, Q Chen, QL Mo, Y Wu, FX **ao - Journal of Materials …, 2023 - pubs.rsc.org
Photocatalysis has been regarded as an emerging technology to convert renewable solar
energy to chemical fuels, providing unprecedented opportunities for solving the deteriorating …
energy to chemical fuels, providing unprecedented opportunities for solving the deteriorating …
Creation of High‐Performance Heterogeneous Photocatalysts by Controlling Ligand Desorption and Particle Size of Gold Nanocluster
T Kawawaki, Y Kataoka, M Hirata… - Angewandte Chemie …, 2021 - Wiley Online Library
Recently, the creation of new heterogeneous catalysts using the unique electronic/geometric
structures of small metal nanoclusters (NCs) has received considerable attention. However …
structures of small metal nanoclusters (NCs) has received considerable attention. However …
Thiolate‐protected metal nanoclusters: recent development in synthesis, understanding of reaction, and application in energy and environmental field
T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …
great potential as novel functional materials. Fundamental research on metal NCs gradually …
Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties
S Hossain, D Hirayama, A Ikeda, M Ishimi… - …, 2023 - Wiley Online Library
Thiolate (SR)‐protected gold nanoclusters (Aun (SR) m NCs) are a rare type of material
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …