Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

A theory/experience description of support effects in carbon-supported catalysts

IC Gerber, P Serp - Chemical Reviews, 2019 - ACS Publications
The support plays an important role for supported metal catalysts by positioning itself as a
macromolecular ligand, which conditions the nature of the active site and contributes …

When bimetallic oxides and their complexes meet Fenton-like process

W Fu, J Yi, M Cheng, Y Liu, G Zhang, L Li, L Du… - Journal of Hazardous …, 2022 - Elsevier
The heterogeneous Fenton-like reaction is an advanced oxidation process, which is widely
recognized for its efficient removal of recalcitrant organic contaminants. In recent years, the …

Design and fabrication of mesoporous heterogeneous basic catalysts

LB Sun, XQ Liu, HC Zhou - Chemical Society Reviews, 2015 - pubs.rsc.org
Mesoporous solid bases are extremely desirable in green catalytic processes, due to their
advantages of accelerated mass transport, negligible corrosion, and easy separation. Great …

Enhanced catalysis based on the surface environment of the silica-supported metal complex

K Motokura, S Ding, K Usui, Y Kong - ACS Catalysis, 2021 - ACS Publications
Silica-supported metal complex catalysts have been developed and used for organic
transformations. The surface environment around the supported metal complex enhances …

Recent advances on polyoxometalates intercalated layered double hydroxides: From synthetic approaches to functional material applications

S Omwoma, W Chen, R Tsunashima… - Coordination Chemistry …, 2014 - Elsevier
Polyoxometalates (POMs) exhibit attractive properties and great potential to meet with
contemporary society demands regarding environment, materials, energy, health and …

Chiral catalysts immobilized on achiral polymers: effect of the polymer support on the performance of the catalyst

B Altava, MI Burguete, E García-Verdugo… - Chemical Society …, 2018 - pubs.rsc.org
Positive effects of the polymeric support on the performance of supported chiral catalysts, in
terms of activity, stability and selectivity–enantioselectivity, have been reported when the …

Cp* Rh-based heterometallic metallarectangles: size-dependent Borromean link structures and catalytic acyl transfer

SL Huang, YJ Lin, TSA Hor, GX ** - Journal of the American …, 2013 - ACS Publications
A series of Cp* Rh-based functional metallarectangles have been synthesized from
metallaligands. Enlargement of one linker leads to the isolation of two novel Borromean link …

Bi-functional NH 2-MIL-101 (Fe) for one-pot tandem photo-oxidation/Knoevenagel condensation between aromatic alcohols and active methylene compounds

D Wang, Z Li - Catalysis Science & Technology, 2015 - pubs.rsc.org
Tandem reactions, which enable multistep reactions in one pot, offer enormous economical
advantages. For the first time, this manuscript reported that NH2-MIL-101 (Fe), an earth …

Selective glucose conversion to 5-hydroxymethylfurfural (5-HMF) instead of levulinic acid with MIL-101Cr MOF-derivatives

A Herbst, C Janiak - New Journal of Chemistry, 2016 - pubs.rsc.org
The catalytic conversion of glucose to 5-hydroxymethylfurfural (5-HMF) is highly desirable,
but the 5-HMF yield obtained using heterogeneous catalysts is still low compared to …