Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Aromatic hydrocarbon belts

QH Guo, Y Qiu, MX Wang, J Fraser Stoddart - Nature chemistry, 2021 - nature.com
Aromatic hydrocarbon belts (AHCBs) have fascinated scientists for over half a century
because of their aesthetically appealing structures and potential applications in the field of …

Synthesis of a carbon nanobelt

G Povie, Y Segawa, T Nishihara, Y Miyauchi, K Itami - Science, 2017 - science.org
The synthesis of a carbon nanobelt, comprising a closed loop of fully fused edge-sharing
benzene rings, has been an elusive goal in organic chemistry for more than 60 years. Here …

Structurally uniform and atomically precise carbon nanostructures

Y Segawa, H Ito, K Itami - Nature Reviews Materials, 2016 - nature.com
Nanometre-sized carbon materials consisting of benzene units oriented in unique geometric
patterns, hereafter named nanocarbons, conduct electricity, absorb and emit light, and …

Conjugated nanohoops incorporating donor, acceptor, hetero‐or polycyclic aromatics

M Hermann, D Wassy, B Esser - Angewandte Chemie, 2021 - Wiley Online Library
In the last 13 years several synthetic strategies were developed that provide access to [n]
cycloparaphenylenes ([n] CPPs) and related conjugated nanohoops. A number of potential …

The dynamic, size-dependent properties of [5]–[12] cycloparaphenylenes

ER Darzi, R Jasti - Chemical Society Reviews, 2015 - pubs.rsc.org
[n] Cycloparaphenylenes (or “carbon nanohoops”) are cyclic fragments of carbon nanotubes
that consist of n para linked benzene rings. These strained, all sp2 hybridized macrocycles …

Design and synthesis of carbon nanotube segments

Y Segawa, A Yagi, K Matsui… - Angewandte Chemie …, 2016 - Wiley Online Library
The selective and predictable synthesis of structurally uniform carbon nanotubes (CNTs)
represents a long‐standing goal in both nanocarbon science and synthetic organic …

Nucleus-independent chemical shifts (NICS) as an aromaticity criterion

Z Chen, CS Wannere, C Corminboeuf, R Puchta… - Chemical …, 2005 - ACS Publications
Few concepts are as frequently used as aromaticity in the current chemical literature. 1 This
may be quantified by ca. 300 000 papers dealing with the aromatic properties of chemical …

Radical reactions of fullerenes: from synthetic organic chemistry to materials science and biology

MD Tzirakis, M Orfanopoulos - Chemical reviews, 2013 - ACS Publications
Since their discovery in 1985 1 and their production on a preparative scale 5 years later, 2
fullerenes have attracted a great deal of attention. Their chemical modification has emerged …

Functionalized fullerenes in water. The first 10 years of their chemistry, biology, and nanoscience

E Nakamura, H Isobe - Accounts of chemical research, 2003 - ACS Publications
Fullerenes are entirely insoluble in water, but suitable functionalization makes the molecules
soluble. Studies on water-soluble fullerene derivatives led to the discovery of the interaction …