Mechanisms of autocatalysis
Self‐replication is a fundamental concept. The idea of an entity that can repeatedly create
more of itself has captured the imagination of many thinkers from von Neumann to …
more of itself has captured the imagination of many thinkers from von Neumann to …
Autocatalytic models for the origin of biological homochirality
DG Blackmond - Chemical reviews, 2019 - ACS Publications
Autocatalytic models for the emergence of homochirality have been of interest for more than
half a century. The sole experimental example of such an amplifying autocatalytic reaction is …
half a century. The sole experimental example of such an amplifying autocatalytic reaction is …
Circularly polarized light with sense and wavelengths to regulate azobenzene supramolecular chirality in optofluidic medium
Circularly polarized light (CPL) as a massless physical force causes absolute asymmetric
photosynthesis, photodestruction, and photoresolution. CPL handedness has long been …
photosynthesis, photodestruction, and photoresolution. CPL handedness has long been …
Asymmetric autocatalysis of pyrimidyl alkanol and its application to the study on the origin of homochirality
K Soai, T Kawasaki, A Matsumoto - Accounts of Chemical …, 2014 - ACS Publications
Conspectus Amplification of enantiomeric excess (ee) is a key feature for the chemical
evolution of biological homochirality from the origin of chirality. We describe the amplification …
evolution of biological homochirality from the origin of chirality. We describe the amplification …
Asymmetric autocatalysis. Chiral symmetry breaking and the origins of homochirality of organic molecules
K Soai - Proceedings of the Japan Academy, Series B, 2019 - jstage.jst.go.jp
Biological homochirality, such as that of l-amino acids, has been a puzzle with regards to the
chemical origin of life. Asymmetric autocatalysis is a reaction in which a chiral product acts …
chemical origin of life. Asymmetric autocatalysis is a reaction in which a chiral product acts …
Crystal structure of the isopropylzinc alkoxide of pyrimidyl alkanol: mechanistic insights for asymmetric autocatalysis with amplification of enantiomeric excess
A Matsumoto, T Abe, A Hara, T Tobita… - Angewandte …, 2015 - Wiley Online Library
Asymmetric amplification during self‐replication is a key feature that is used to explain the
origin of homochirality. Asymmetric autocatalysis of pyrimidyl alkanol in the asymmetric …
origin of homochirality. Asymmetric autocatalysis of pyrimidyl alkanol in the asymmetric …
Absolute asymmetric synthesis in enantioselective autocatalytic reaction networks: Theoretical games, speculations on chemical evolution and perhaps a synthetic …
The Soai reaction and the Viedma deracemization of racemic conglomerate crystal mixtures
are experimental pieces of evidence of the ability of enantioselective autocatalytic coupled …
are experimental pieces of evidence of the ability of enantioselective autocatalytic coupled …
Quantification of sophisticated equilibria in the reaction pool and amplifying catalytic cycle of the Soai reaction
ID Gridnev, AK Vorobiev - ACS Catalysis, 2012 - ACS Publications
The relative abundance of various species in the reaction pool of the Soai autoamplification
reaction was estimated by large-scale density functional theory (DFT) computations …
reaction was estimated by large-scale density functional theory (DFT) computations …
Asymmetric autocatalysis of pyrimidyl alkanol and related compounds. Self-replication, amplification of chirality and implication for the origin of biological …
K Soai, T Kawasaki, A Matsumoto - Tetrahedron, 2018 - Elsevier
We discovered asymmetric autocatalysis in the enantioselective addition of diisopropylzinc
to pyrimidine-5-carbaldehyde, where the product 5-pyrimidyl alkanol acts as a highly …
to pyrimidine-5-carbaldehyde, where the product 5-pyrimidyl alkanol acts as a highly …
Formation of enantioenriched alkanol with stochastic distribution of enantiomers in the absolute asymmetric synthesis under heterogeneous solid–vapor phase …
Y Kaimori, Y Hiyoshi, T Kawasaki… - Chemical …, 2019 - pubs.rsc.org
Among several theories proposed for the origin of homochirality, absolute asymmetric
synthesis is unique because it produces chiral compounds without the intervention of any …
synthesis is unique because it produces chiral compounds without the intervention of any …