Historical landmarks of the application of molecular transition metal catalysts for olefin epoxidation

S Huber, M Cokoja, FE Kuehn - Journal of organometallic chemistry, 2014 - Elsevier
Various polymers, fine chemicals, pharmaceuticals, food additives and flavor & fragrance
compounds are based on epoxide intermediates. This historical perspective covers the …

N-heterocyclic carbene complexes of Group 6 metals

Z Wang, L Jiang, DKB Mohamed, J Zhao… - Coordination Chemistry …, 2015 - Elsevier
Across the periodic table, Group 6 metals (Cr, Mo, W) play an important role in the
development of carbene chemistry. In this review, we highlight the synthetic methodologies …

Syntheses, structural characterizations, and catalytic activities of manganese (II)-aroylhydrazone complexes

L Nishana, A Sakthivel, MRP Kurup - Journal of Molecular Structure, 2023 - Elsevier
Abstract An aroylhydrazone, di-2-pyridyl ketone-4-methoxybenzhydrazone monohydrate
(DKMBH· H 2 O), and its three Mn (II) complexes,[Mn (DKMB) 2]· H 2 O (1),[Mn (DKMB) …

Olefin Epoxidation Catalyzed by η5-Cyclopentadienyl Molybdenum Compounds: A Computational Study

PJ Costa, MJ Calhorda, FE Kühn - Organometallics, 2010 - ACS Publications
η5-Cyclopentadienyl (tricarbonyl) methylmolybdenum (II)(1) is oxidized by tert-
butylhydroperoxide (TBHP) to yield η5-cyclopentadienyl (dioxo) methylmolybdenum (VI)(2) …

Pd-grafted functionalized mesoporous MCM-41: a novel, green and heterogeneous nanocatalyst for the selective synthesis of phenols and anilines from aryl halides …

F Havasi, A Ghorbani-Choghamarani… - New Journal of …, 2015 - pubs.rsc.org
A new type of mesoporous-recoverable catalyst was synthesized by the immobilization of Pd
on the surface of functionalized mesoporous MCM-41 and used as an efficient, recoverable …

Optimizing acid− base bifunctional mesoporous catalysts for the henry reaction: effects of the surface density and site isolation of functional groups

KK Sharma, RP Buckley, T Asefa - Langmuir, 2008 - ACS Publications
We report on the effects of the surface density and the spacing between grafted
organoamines (and residual ungrafted silanols) of amine-functionalized mesoporous …

Olefin Epoxidation by H2O2/MeCN Catalysed by Cyclopentadienyloxidotungsten(VI) and Molybdenum(VI) Complexes: Experiments and Computations

C Dinoi, M Ciclosi, E Manoury, L Maron… - … A European Journal, 2010 - Wiley Online Library
Abstract Compounds [Cp* 2M2O5](M= Mo, 1; W, 2) are efficient pre‐catalysts for cyclooctene
(COE) epoxidation by aqueous H2O2 in acetonitrile/toluene. The reaction is quantitative …

Synthesis and catalytic applications of chiral monomeric organomolybdenum (VI) and organorhenium (VII) oxides in homogeneous and heterogeneous phase

KR Jain, WA Herrmann, FE Kühn - Coordination Chemistry Reviews, 2008 - Elsevier
In recent years several attempts have been made to introduce chirality into organometallic
Re (VII) compounds of formula RReO3 and related organometallic complexes containing the …

Anchoring of Pd (II) complex in functionalized MCM-41 as an efficient and recoverable novel nano catalyst in C–C, C–O and C–N coupling reactions using Ph 3 SnCl

A Ghorbani-Choghamarani, F Nikpour, F Ghorbani… - RSC Advances, 2015 - pubs.rsc.org
Anchored palladium (II) in functionalized MCM-41 mesoporous silica was prepared and
used as an efficient, recoverable and thermally stable heterogeneous nano catalyst for C–C …

Evolved gas analysis by mass spectrometry

S Materazzi, S Vecchio - Applied Spectroscopy Reviews, 2011 - Taylor & Francis
The analytical applications of the evolved gas analyses (EGAs) performed by mass
spectrometry for the period extending from 2005 to 2010 are collected in this review. By …