Highly regioselective addition of allylic zinc halides and various zinc enolates to [1.1. 1] propellane
K Schwärzer, H Zipse, K Karaghiosoff… - Angewandte Chemie …, 2020 - Wiley Online Library
We report a range of highly regioselective openings of [1.1. 1] propellane with various allylic
zinc halides, as well as zinc enolates of ketones, esters and nitriles. The resulting zincated …
zinc halides, as well as zinc enolates of ketones, esters and nitriles. The resulting zincated …
Transition‐Metal‐Free Synthesis of Polyfunctional Triarylmethanes and 1, 1‐Diarylalkanes by Sequential Cross‐Coupling of Benzal Diacetates with Organozinc …
A variety of functionalized triarylmethane and 1, 1‐diarylalkane derivatives were prepared
via a transition‐metal‐free, one‐pot and two‐step procedure, involving the reaction of …
via a transition‐metal‐free, one‐pot and two‐step procedure, involving the reaction of …
A Zinc Catalyzed C(sp3)−C(sp2) Suzuki–Miyaura Cross‐Coupling Reaction Mediated by Aryl‐Zincates
RJ Procter, JJ Dunsford, PJ Rushworth… - … A European Journal, 2017 - Wiley Online Library
Abstract The Suzuki–Miyaura (SM) reaction is one of the most important methods for C− C
bond formation in chemical synthesis. In this communication, we show for the first time that …
bond formation in chemical synthesis. In this communication, we show for the first time that …
Transition‐Metal‐Free Approaches to Arylsulfones using Benzylic Ammonium Salts through C− N Bond Cleavage
Y Liu, H Zhu, L Yang, Z **e, G Jiang… - Asian Journal of …, 2020 - Wiley Online Library
A transition‐metal‐free approach to benzyl sulfones by using sodium sulfinates and benzyl
ammonium salts is described. The protocol provides a simple and direct method to realize …
ammonium salts is described. The protocol provides a simple and direct method to realize …
Preparation of Functionalized Diorganomagnesium Reagents in Toluene via Bromine or Iodine/Magnesium-Exchange Reactions
A Desaintjean, F Danton, P Knochel - Synthesis, 2021 - thieme-connect.com
A wide range of polyfunctionalized di (hetero) aryl-and dialkenyl-magnesium reagents are
prepared in toluene within 10 to 120 minutes between–78° C and 25° C via an I/Mg-or Br/Mg …
prepared in toluene within 10 to 120 minutes between–78° C and 25° C via an I/Mg-or Br/Mg …
Synthese von Polyketiden mittels Matteson-Homologisierung
O Andler - 2022 - publikationen.sulb.uni-saarland.de
Diese Doktorarbeit behandelt die Synthese komplexer Polyketid-Naturstoffe mittels
Matteson-Homologisierung. Hierzu wurden neue bzw. bisher wenig in dieser Reaktion …
Matteson-Homologisierung. Hierzu wurden neue bzw. bisher wenig in dieser Reaktion …