The distance between phosphate‐based polyanionic compounds and their practical application for sodium‐ion batteries

Z Hao, X Shi, Z Yang, X Zhou, L Li, CQ Ma… - Advanced …, 2024 - Wiley Online Library
Sodium‐ion batteries (SIBs) are a viable alternative to meet the requirements of future large‐
scale energy storage systems due to the uniform distribution and abundant sodium …

From Lab to Application: Challenges and Opportunities in Achieving Fast Charging with Polyanionic Cathodes for Sodium‐Ion Batteries

X Lu, S Li, Y Li, F Wu, C Wu, Y Bai - Advanced Materials, 2024 - Wiley Online Library
Abstract Sodium‐ion batteries (SIBs), recognized for balanced energy density and cost‐
effectiveness, are positioned as a promising complement to lithium‐ion batteries (LIBs) and …

Reversible multielectron redox chemistry in a NASICON‐type cathode toward high‐energy‐density and long‐life sodium‐ion full batteries

Y Zhou, G Xu, J Lin, Y Zhang, G Fang… - Advanced …, 2023 - Wiley Online Library
Abstract Na‐superionic‐conductor (NASICON)‐type cathodes (eg, Na3V2 (PO4) 3) have
attracted extensive attention due to their open and robust framework, fast Na+ mobility, and …

Homeostatic solid solution reaction in phosphate cathode: breaking high‐voltage barrier to achieve high energy density and long life of sodium‐ion batteries

ZY Gu, XX Zhao, K Li, JM Cao, XT Wang… - Advanced …, 2024 - Wiley Online Library
The stable phase transformation during electrochemical progress drives extensive research
on vanadium‐based polyanions in sodium‐ion batteries (SIBs), especially Na3V2 (PO4) 3 …

Boosting multielectron reaction stability of sodium vanadium phosphate by high-entropy substitution

Z Hao, X Shi, W Zhu, Z Yang, X Zhou, C Wang, L Li… - ACS …, 2024 - ACS Publications
Na3V2 (PO4) 3 (NVP) based on the multielectron reactions between V2+ and V5+ has been
considered a promising cathode for sodium-ion batteries (SIBs). However, it still suffers from …

Unlocking Charge Transfer Limitation in NASICON Structured Na3V2(PO4)3 Cathode via Trace Carbon Incorporation

R Huang, D Yan, Q Zhang, G Zhang… - Advanced Energy …, 2024 - Wiley Online Library
NASICON‐type cathode with remarkable ionic conductivity is perspective candidate for fast‐
charging sodium‐ion battery. However, severely restricted by low electrical conductivity and …

NaSICON: A promising solid electrolyte for solid‐state sodium batteries

C Li, R Li, K Liu, R Si, Z Zhang… - Interdisciplinary …, 2022 - Wiley Online Library
A surge of interest has been brought to all‐solid‐state batteries (ASSBs) as they show great
prospects for enabling higher energy density and improved safety compared to conventional …

Unlocking Quasi‐Monophase Behavior in NASICON Cathode to Drive Fast‐Charging Toward Durable Sodium‐Ion Batteries

XX Zhao, XT Wang, ZY Gu, JZ Guo… - Advanced Functional …, 2024 - Wiley Online Library
Abstract The NASICON cathode, Na3V2 (PO4) 3, has garnered significant attention due to
its robust framework with fast Na+ migration. To expand its application scenarios by …

Na2.5VTi0.5Al0.5(PO4)3 as Long Lifespan Cathode for Fast Charging Sodium‐Ion Batteries

Z Li, C Sun, M Li, X Wang, Y Li, X Yuan… - Advanced Functional …, 2024 - Wiley Online Library
Vanadium based NASICON‐type cathodes are faced with the exorbitant cost and
underdeveloped multi‐electrons reaction of V species. In this work, a strategy of increased …

Improving Rate Performance by Inhibiting Jahn–Teller Effect in Mn‐Based Phosphate Cathode for Na‐Ion Batteries

C Sun, Q Ni, M Li, Z Sun, X Yuan, L Li… - Advanced Functional …, 2024 - Wiley Online Library
Manganese‐based phosphate cathodes are promising candidates for develo** advanced
sodium‐ion batteries, primarily driven by their reliable elemental abundance, low toxicity …