[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Symmetry strategies for high performance lanthanide-based single-molecule magnets

JL Liu, YC Chen, ML Tong - Chemical Society Reviews, 2018 - pubs.rsc.org
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

Computational discovery of transition-metal complexes: from high-throughput screening to machine learning

A Nandy, C Duan, MG Taylor, F Liu, AH Steeves… - Chemical …, 2021 - ACS Publications
Transition-metal complexes are attractive targets for the design of catalysts and functional
materials. The behavior of the metal–organic bond, while very tunable for achieving target …

Improving f-element single molecule magnets

ST Liddle, J van Slageren - Chemical Society Reviews, 2015 - pubs.rsc.org
Ever since the discovery that certain manganese clusters retain their magnetisation for
months at low temperatures, there has been intense interest in molecular nanomagnets …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Molecular magnetism of lanthanide: Advances and perspectives

Z Zhu, M Guo, XL Li, J Tang - Coordination Chemistry Reviews, 2019 - Elsevier
The discovery of the first example of lanthanide-based single molecule magnets (Ln-SMMs),
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …

Ab initio prediction of high-temperature magnetic relaxation rates in single-molecule magnets

D Reta, JGC Kragskow, NF Chilton - Journal of the American …, 2021 - ACS Publications
Organometallic molecules based on [Dy (CpR) 2]+ cations (where CpR is a substituted
cyclopentadienyl anion) have emerged as clear front-runners in the search for high …

Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing only one lanthanide ion

HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2014 - Elsevier
A very basic tutorial-style introduction to Single-Molecule Magnetism, intended for a general
chemistry audience, is provided. This is followed by a review of the synthesis, structures and …

Understanding the magnetic anisotropy toward single-ion magnets

YS Meng, SD Jiang, BW Wang… - Accounts of chemical …, 2016 - ACS Publications
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …

Single ion magnets from 3d to 5f: developments and strategies

M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …