Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Effects of Fe oxides and their redox cycling on Cd activity in paddy soils: a review

Y Gao, H Tong, Z Zhao, N Cheng, P Wu - Journal of Hazardous Materials, 2023 - Elsevier
Cadmium (Cd) contamination of soils is a global problem, particularly in paddy soils. Fe
oxides, as a key fraction of paddy soils, can significantly affect the environmental behavior of …

Redox oscillations activate thermodynamically stable iron minerals for enhanced reactive oxygen species production

G Zhao, M Tan, B Wu, X Zheng, R **ong… - Environmental …, 2023 - ACS Publications
Reactive oxygen species (ROS) play key roles in driving biogeochemical processes. Recent
studies have revealed nonphotochemical electron transfer from redox-active substances …

Schwertmannite: A review of its occurrence, formation, structure, stability and interactions with oxyanions

VA Schoepfer, ED Burton - Earth-Science Reviews, 2021 - Elsevier
In this article, we provide a critical review on the occurrence, formation, structure and stability
of schwertmannite–an enigmatic Fe (III) oxyhydroxy-sulfate mineral that is of widespread …

Multiple effects of humic components on microbially mediated iron redox processes and production of hydroxyl radicals

R Han, Z Wang, J Lv, Z Zhu, GH Yu, G Li… - … Science & Technology, 2022 - ACS Publications
Microbially mediated iron redox processes are of great significance in the biogeochemical
cycles of elements, which are often coupled with soil organic matter (SOM) in the …

Fe (II)-catalyzed transformation of ferrihydrite with different degrees of crystallinity

Y Liu, Y Ding, A Sheng, X Li, J Chen… - … Science & Technology, 2023 - ACS Publications
Natural occurring ferrihydrite (Fh) nanoparticles have varying degrees of crystallinity, but
how Fh crystallinity affects its transformation behavior remains elusive. Here, we …

Reductive sequestration of Cr (VI) and immobilization of C during the microbially mediated transformation of Ferrihydrite-Cr (VI)-fulvic acid coprecipitates

S Hu, H Zhang, Y Yang, W Wang, W Zhou… - Environmental …, 2023 - ACS Publications
Cr (VI) detoxification and organic matter (OM) stabilization are usually influenced by the
biological transformation of iron (Fe) minerals; however, the underlying mechanisms of …

Coexisting goethite promotes Fe (II)-catalyzed transformation of ferrihydrite to goethite

L Notini, LK ThomasArrigo, R Kaegi… - … Science & Technology, 2022 - ACS Publications
In redox-affected soil environments, electron transfer between aqueous Fe (II) and solid-
phase Fe (III) catalyzes mineral transformation and recrystallization processes. While these …

Stabilization of ferrihydrite and lepidocrocite by silicate during Fe (II)-catalyzed mineral transformation: Impact on particle morphology and silicate distribution

K Schulz, LK ThomasArrigo, R Kaegi… - Environmental …, 2022 - ACS Publications
Interactions between aqueous ferrous iron (Fe (II)) and secondary Fe oxyhydroxides
catalyze mineral recrystallization and/or transformation processes in anoxic soils and …

Cadmium isotope fractionation during adsorption and substitution with iron (oxyhydr) oxides

X Yan, M Zhu, W Li, CL Peacock, J Ma… - … science & technology, 2021 - ACS Publications
Cadmium (Cd) isotopes have great potential for understanding Cd geochemical cycling in
soil and aquatic systems. Iron (oxyhydr) oxides can sequester Cd via adsorption and …