Molecular views on mechanisms of brønsted acid-catalyzed reactions in zeolites

C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …

High-entropy materials for catalysis: A new frontier

Y Sun, S Dai - Science advances, 2021 - science.org
Entropy plays a pivotal role in catalysis, and extensive research efforts have been directed to
understanding the enthalpy-entropy relationship that defines the reaction pathways of …

Recent advances in the routes and catalysts for ethanol synthesis from syngas

G Liu, G Yang, X Peng, J Wu, N Tsubaki - Chemical Society Reviews, 2022 - pubs.rsc.org
Ethanol, as one of the important bulk chemicals, is widely used in modern society. It can be
produced by fermentation of sugar, petroleum refining, or conversion of syngas (CO/H2) …

Confining isolated atoms and clusters in crystalline porous materials for catalysis

L Liu, A Corma - Nature Reviews Materials, 2021 - nature.com
Abstract Structure–reactivity relationships for nanoparticle-based catalysts have been
greatly influenced by the study of catalytic materials with either supported isolated metal …

Activation and conversion of alkanes in the confined space of zeolite-type materials

P Del Campo, C Martínez, A Corma - Chemical Society Reviews, 2021 - pubs.rsc.org
Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …

Advances in theory and their application within the field of zeolite chemistry

V Van Speybroeck, K Hemelsoet, L Joos… - Chemical Society …, 2015 - pubs.rsc.org
Zeolites are versatile and fascinating materials which are vital for a wide range of industries,
due to their unique structural and chemical properties, which are the basis of applications in …

Post-synthesis modification of metal–organic frameworks: synthesis, characteristics, and applications

W He, D Lv, Y Guan, S Yu - Journal of Materials Chemistry A, 2023 - pubs.rsc.org
Post-synthesis modification (PSM) is an efficient means to introduce functional chemical
groups into metal–organic frameworks (MOFs) by modifying metal clusters or ligands after …

Controlling the isolation and pairing of aluminum in chabazite zeolites using mixtures of organic and inorganic structure-directing agents

JR Di Iorio, R Gounder - Chemistry of Materials, 2016 - ACS Publications
Synthetic methods are reported to prepare chabazite (CHA) zeolites (SSZ-13) at fixed
elemental composition but with different arrangements of their framework Al atoms (Al–O …

Recent advances in catalytic confinement effect within micro/meso‐porous crystalline materials

J Dai, H Zhang - Small, 2021 - Wiley Online Library
Micro/meso‐porous crystalline materials with a well‐defined pore structure, such as zeolites,
carbon nanotubes, and metal–organic frameworks, are of great significance in the …

Structural transformations of solid electrocatalysts and photocatalysts

L Liu, A Corma - Nature reviews chemistry, 2021 - nature.com
Heterogeneous catalysts often undergo structural transformations when they operate under
thermal reaction conditions. These transformations are reflected in their evolving catalytic …