The n→π* Interaction

RW Newberry, RT Raines - Accounts of chemical research, 2017 - ACS Publications
Conspectus The carbonyl group holds a prominent position in chemistry and biology not
only because it allows diverse transformations but also because it supports key …

C–H⋯ S hydrogen bonding interactions

HA Fargher, TJ Sherbow, MM Haley… - Chemical Society …, 2022 - pubs.rsc.org
The short C–H⋯ S contacts found in available structural data for both small molecules and
larger biomolecular systems suggest that such contacts are an often overlooked yet …

Peptoid nanosheets exhibit a new secondary-structure motif

RV Mannige, TK Haxton, C Proulx, EJ Robertson… - Nature, 2015 - nature.com
A promising route to the synthesis of protein-mimetic materials that are capable of complex
functions, such as molecular recognition and catalysis, is provided by sequence-defined …

Combining mass spectrometric metabolic profiling with genomic analysis: a powerful approach for discovering natural products from cyanobacteria

K Kleigrewe, J Almaliti, IY Tian, RB Kinnel… - Journal of natural …, 2015 - ACS Publications
An innovative approach was developed for the discovery of new natural products by
combining mass spectrometric metabolic profiling with genomic analysis and resulted in the …

Small molecular antibacterial peptoid mimics: the simpler the better!

C Ghosh, GB Manjunath, P Akkapeddi… - Journal of medicinal …, 2014 - ACS Publications
The emergence of multidrug resistant bacteria compounded by the depleting arsenal of
antibiotics has accelerated efforts toward development of antibiotics with novel mechanisms …

Palladium‐Catalyzed Enantioselective C− H Olefination to Access Planar‐Chiral Cyclophanes by Dynamic Kinetic Resolution

Z Dong, J Li, T Yao, C Zhao - … Chemie International Edition, 2023 - Wiley Online Library
Planar‐chiral cyclophanes have received increasing attention for drug discovery and
catalyst design. However, the catalytically asymmetric synthesis of planar‐chiral …

NDTP mediated direct rapid amide and peptide synthesis without epimerization

Y Li, J Li, G Bao, C Yu, Y Liu, Z He, P Wang, W Ma… - Organic …, 2022 - ACS Publications
Herein, we explored an unprecedented mild, nonirritating, conveniently available, and
recyclable coupling reagent NDTP, which could activate the carboxylic acids via acyl …

Time and Atom Economical Regio‐and Chemoselective Radical Cyclization of Unactivated 1, 6‐Enynes Under Metal‐and Oxidant‐Free Conditions

MR Mutra, J Li, YT Chen… - Chemistry–A European …, 2022 - Wiley Online Library
We developed time‐atom economic regio‐and chemoselective sulfonyl radical triggered 5‐
exo‐dig cyclization of unactivated 1, 6‐enynes with sulfonyl halides under metal, additive …

Cooperative Intramolecular Hydrogen Bonding Strongly Enforces cis-Peptoid Folding

AW Wijaya, AI Nguyen, LT Roe… - Journal of the …, 2019 - ACS Publications
Sequence-defined peptoids, or N-substituted glycines, are an attractive class of bioispired
polymer due to their biostability and efficient synthesis. However, the de novo design of …

Three-component reaction between alkynes, elemental sulfur, and aliphatic amines: a general, straightforward, and atom economical approach to thioamides

TB Nguyen, MQ Tran, L Ermolenko… - Organic letters, 2014 - ACS Publications
Three-Component Reaction between Alkynes, Elemental Sulfur, and Aliphatic Amines: A
General, Straightforward, and Atom Economical Approach to Thioamides | Organic Letters …