Organic compounds labeled with hydrogen isotopes play a crucial role in numerous areas,
from materials science to medicinal chemistry. Indeed, while the replacement of hydrogen by …

C–H deuteration has been intricately developed to satisfy the urgent need for site-selectively
deuterated organic frameworks. Deuteration has been primarily used to study kinetic isotope …

Herein we describe a general, mild and scalable method for deuterium incorporation by
potassium methoxide/hexamethyldisilane-mediated dehalogenation of arylhalides. With …

In contrast to transition metal-catalysed C–H functionalisation, highly efficient construction of
C–C and C–X (X= N, O, S, B, Si, etc.) bonds through metal-free catalytic C–H …

Deuterium‐labeled compounds are of importance in chemical, environmental, and
biological fields. Preparation methods for deuterium‐labeled compounds have been studied …

There is a constant need for deuterium‐labelled products for multiple applications in life
sciences and beyond. Here, a new class of heterogeneous catalysts is reported for practical …

Transition metal catalyzed C− H functionalization of organic compounds has proved to be a
useful atom‐efficient strategy in organic synthesis. In contrast, main‐group‐element‐based …

Herein, novel photoinduced catalyst-free deborylation–deuteration of arylboronic acids with
D2O is reported. The protocol was compatible with a variety of functionalities, including …

Without the addition of any additives and production of any small molecules, C3-borylated
indoles and transfer hydrogenated indolines have been simultaneously achieved by a B …

Anilines are core motifs in a variety of important molecules including medicines, materials
and agrochemicals. We report a straightforward procedure that allows access to new …