The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Molpro is a general purpose quantum chemistry software package with a long development
history. It was originally focused on accurate wavefunction calculations for small molecules …

Intramolecular aminations of C–H bonds represent an elegant synthetic way to form
important N-heterocycles. If suitable nitrene precursors are employed, organometallic …

The “curly arrow” of Robinson and Ingold is the primary tool for describing and rationalizing
reaction mechanisms. Despite this approach's ubiquity and stellar success, its physical basis …

We introduce the atomic valence active space (AVAS), a simple and well-defined automated
technique for constructing active orbital spaces for use in multiconfiguration and …

The nucleophilic iron complex Bu4N [Fe (CO) 3 (NO)](TBA [Fe]) catalyzes the direct
intramolecular C− H amination of α‐azidobiaryls and (azidoaryl) alkenes into the …

Racemic cyclopropyl ketones undergo enantioselective rearrangement to deliver the
corresponding dihydrofurans in the presence of a chiral phosphoric acid as the catalyst. The …

Iron‐Catalyzed Intramolecular Aminations of C(sp3)−H Bonds in Alkylaryl Azides - Alt - 2017 -
Angewandte Chemie International Edition - Wiley Online Library Skip to Article Content Skip to …

The first example of iron‐catalyzed decarboxylative (4+ 1) cycloaddition reactions is
described in this publication. By using this method, a wide range of functionalized indoline …

An organocatalytic Cloke–Wilson rearrangement of cyclopropyl ketones to 2, 3-
dihydrofurans is exploited utilizing the homoconjugate addition process. With 1, 4 …