Electronic defects in metal oxide photocatalysts

E Pastor, M Sachs, S Selim, JR Durrant… - Nature Reviews …, 2022 - nature.com
A deep understanding of defects is essential for the optimization of materials for solar energy
conversion. This is particularly true for metal oxide photo (electro) catalysts, which typically …

Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

Polarons in materials

C Franchini, M Reticcioli, M Setvin… - Nature Reviews Materials, 2021 - nature.com
Polarons are quasiparticles that easily form in polarizable materials due to the coupling of
excess electrons or holes with ionic vibrations. These quasiparticles manifest themselves in …

Oxalated zero valent iron enables highly efficient heterogeneous Fenton reaction by self-adapting pH and accelerating proton cycle

X Zhang, H Sun, Y Shi, C Ling, M Li, C Liang, F Jia… - Water research, 2023 - Elsevier
Heterogeneous Fenton reactions of zero-valent iron (ZVI) requires the sufficient release of
Fe (II) to catalyze the H 2 O 2 decomposition. However, the rate-limiting step of proton …

Imaging photogenerated charge carriers on surfaces and interfaces of photocatalysts with surface photovoltage microscopy

R Chen, F Fan, T Dittrich, C Li - Chemical Society Reviews, 2018 - pubs.rsc.org
Understanding photogenerated charge separation on the nano-to micrometer scale is the
key to optimizing the photocatalytic solar energy conversion efficiency. In the past few years …

Efficient persulfate activation by hematite nanocrystals for degradation of organic pollutants under visible light irradiation: Facet-dependent catalytic performance and …

T Guo, L Jiang, K Wang, Y Li, H Huang, X Wu… - Applied Catalysis B …, 2021 - Elsevier
Hematite has been well studied in advanced oxidant processes (AOPs) due to its
abundance and non-toxicity, but its precise mechanism in persulfate (PS) activation remains …

Cobalt–iron (oxy) hydroxide oxygen evolution electrocatalysts: the role of structure and composition on activity, stability, and mechanism

MS Burke, MG Kast, L Trotochaud… - Journal of the …, 2015 - ACS Publications
Cobalt oxides and (oxy) hydroxides have been widely studied as electrocatalysts for the
oxygen evolution reaction (OER). For related Ni-based materials, the addition of Fe …

Effects of Fe oxides and their redox cycling on Cd activity in paddy soils: a review

Y Gao, H Tong, Z Zhao, N Cheng, P Wu - Journal of Hazardous Materials, 2023 - Elsevier
Cadmium (Cd) contamination of soils is a global problem, particularly in paddy soils. Fe
oxides, as a key fraction of paddy soils, can significantly affect the environmental behavior of …

High stable photo-Fenton-like catalyst of FeP/Fe single atom-graphene oxide for long-term antibiotic tetracycline removal

X Li, J Hu, Y Deng, T Li, ZQ Liu, Z Wang - Applied Catalysis B …, 2023 - Elsevier
The Fenton-like reaction has always suffered from the disadvantages of narrow pH and poor
stability. Herein, a Fenton-like catalyst with dual-photo-functional sites of iron phosphide …

Excitation-wavelength-dependent small polaron trap** of photoexcited carriers in α-Fe2O3

LM Carneiro, SK Cushing, C Liu, Y Su, P Yang… - Nature materials, 2017 - nature.com
Small polaron formation is known to limit ground-state mobilities in metal oxide
photocatalysts. However, the role of small polaron formation in the photoexcited state and …